TY - JOUR AU - Sarwar, Sidra AU - Sanz, Sergio AU - van Leusen, Jan AU - Nichol, Gary S. AU - Brechin, Euan K. AU - Kögerler, Paul TI - Phthalocyanine-polyoxotungstate lanthanide double deckers JO - Dalton transactions VL - 49 IS - 46 SN - 1477-9234 CY - London PB - Soc. M1 - FZJ-2020-05108 SP - 16638 - 16642 PY - 2020 AB - Acetate ligand metathesis results in the first hybrid [MIII(Pc)(PW11O39)]6− (M = Y, Dy, Tb) double-decker scaffolds, where a phthalocyanate (Pc2−) and one of the conceptually most simple polyoxotungstates, a monolacunary Keggin cluster, are interlinked via a single rare earth ion. Characterisation includes high-resolution mass spectrometry, synchrotron-based single-crystal X-ray diffraction, various spectroscopic and electrochemical methods, and magnetic studies revealing slow relaxation of the magnetisation for the Dy derivate. LB - PUB:(DE-HGF)16 C6 - 33169769 UR - <Go to ISI:>//WOS:000597124500010 DO - DOI:10.1039/D0DT03716H UR - https://juser.fz-juelich.de/record/888673 ER -