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@ARTICLE{Badie:889074,
      author       = {Badie, Sylvain and Dash, Apurv and Sohn, Yoo Jung and
                      Vaßen, Robert and Guillon, Olivier and Gonzalez‐Julian,
                      Jesus},
      title        = {{S}ynthesis, sintering, and effect of surface roughness on
                      oxidation of submicron {T}i 2 {A}l{C} ceramics},
      journal      = {Journal of the American Ceramic Society},
      volume       = {104},
      number       = {4},
      issn         = {1551-2916},
      address      = {Westerville, Ohio},
      publisher    = {Soc.},
      reportid     = {FZJ-2021-00010},
      pages        = {1669-1688},
      year         = {2021},
      abstract     = {Submicron Ti2AlC MAX phase powder was synthesized by molten
                      salt shielded synthesis (MS3) using a Ti:Al:C molar ratio of
                      2:1:0.9 at a process temperature of 1000°C for 5 hours. The
                      synthesized powder presented a mean particle size of ~0.9
                      µm and a purity of 91 wt. $\%$ Ti2AlC, containing 6 wt.
                      $\%$ Ti3AlC2. The Ti2AlC powder was sintered by pressureless
                      sintering, achieving a maximal relative density of $90\%,$
                      hence field‐assisted sintering technology/spark plasma
                      sintering was used to enhance densification. The
                      fine‐grained microstructure was preserved, and phase
                      purity of Ti2AlC was unaltered in the latter case, with a
                      relative density of $98.5\%.$ Oxidation was performed at
                      1200°C for 50 hours in static air of dense monolithic
                      Ti2AlC with different surface finish, (polished, ground and
                      sandblasted) which resulted in the formation of an approx. 8
                      µm thin aluminum oxide (Al2O3) layer decorated with
                      titanium dioxide (rutile, TiO2) colonies. Surface quality
                      had no influence on Al2O3 scale thickness, but the amount
                      and size of TiO2 crystals increased with surface roughness.
                      A phenomenon of rumpling of the thermally grown oxide (TGO)
                      was observed and a model to estimate the extent of
                      deformation is proposed.},
      cin          = {IEK-1 / JARA-ENERGY},
      ddc          = {660},
      cid          = {I:(DE-Juel1)IEK-1-20101013 / $I:(DE-82)080011_20140620$},
      pnm          = {1241 - Gas turbines (POF4-124)},
      pid          = {G:(DE-HGF)POF4-1241},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:000599727500001},
      doi          = {10.1111/jace.17582},
      url          = {https://juser.fz-juelich.de/record/889074},
}