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@ARTICLE{Zhou:890607,
author = {Zhou, Wenyu and Malzbender, Jürgen and Deibert, Wendelin
and Guillon, Olivier and Schwaiger, Ruth and Nijmeijer,
Arian and Meulenberg, Wilhelm Albert},
title = {{H}igh temperature compressive creep behavior of {B}a{C}e
0.65 {Z}r 0.2 {Y} 0.15 {O} 3‐ δ in air and $4\%$ {H} 2
/{A}r},
journal = {Journal of the American Ceramic Society},
volume = {104},
number = {6},
issn = {1551-2916},
address = {Westerville, Ohio},
publisher = {Soc.},
reportid = {FZJ-2021-01069},
pages = {2730-2740},
year = {2021},
abstract = {The proton conductive material BaCe0.65Zr0.2Y0.15O3−δ
has great potential for the separation and purification of
hydrogen. However, due to the demanding application
conditions regarding both temperature and atmosphere, the
elevated temperature structural stability needs to be
characterized and warranted. Hence, in this research work,
the elevated temperature compressive creep behavior of
BaCe0.65Zr0.2Y0.15O3−δ in the temperature regime of
850°C to 1200°C was studied in both air and $4\%$ H2/Ar as
a function of the applied stress. The results indicate
different creep mechanisms depending on atmosphere and
temperature range. While dislocation creep was observed in
$4\%$ H2/Ar over the full range, a dislocation creep
mechanism was observed in air at temperatures ≤1050°C and
a diffusional creep mechanism at temperature ≥1100°C. A
detailed microstructural analysis of the post‐creep test
specimens revealed that the exposure to oxygen leads to
localized stoichiometric changes and a decomposition at the
surface.},
cin = {IEK-1 / IEK-2 / JARA-ENERGY},
ddc = {660},
cid = {I:(DE-Juel1)IEK-1-20101013 / I:(DE-Juel1)IEK-2-20101013 /
$I:(DE-82)080011_20140620$},
pnm = {123 - Chemische Energieträger (POF4-123)},
pid = {G:(DE-HGF)POF4-123},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000618323000001},
doi = {10.1111/jace.17715},
url = {https://juser.fz-juelich.de/record/890607},
}