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@ARTICLE{Korshunov:890729,
author = {Korshunov, Aleksandr and Gibalova, Anna and Grünebaum,
Mariano and Ravoo, Bart Jan and Winter, Martin and
Cekic-Laskovic, Isidora},
title = {{H}ost‐{G}uest {I}nteractions {E}nhance the {P}erformance
of {V}iologen {E}lectrolytes for {A}queous {O}rganic {R}edox
{F}low {B}atteries},
journal = {Batteries $\&$ supercaps},
volume = {4},
number = {6},
issn = {2566-6223},
address = {Weinheim},
publisher = {Wiley-VCH},
reportid = {FZJ-2021-01152},
pages = {923-928},
year = {2021},
abstract = {Host-guest interactions are an attractive approach to
design redox electrolytes, enabling to precisely tune the
key properties for redox flow batteries such as half-cell
redox potential, solubility, and stability. Herein we report
a host-guest complex of highly water soluble
(2-hydroxypropyl)-β-cyclodextrin with
1-decyl-1′-ethyl-4,4′-bipyridinium dibromide as anolyte
in a new aqueous organic redox flow battery (AORFB). The
supramolecular anolyte ensured the total RFB voltage
increase of $≈9 \%$ up to 0.97 V and provided a stable
capacity delivery for more than 500 cycles with a capacity
fade rate of $0.037 \%/cycle$ $(2.84 \%/day)$ at high
Coulombic $(>99.5 \%)$ and energy $(>62 \%)$
efficiencies. The results highlight host-guest interactions
as promising strategy towards more effective storage of
renewable energy within AORFBs.},
cin = {IEK-12},
ddc = {620},
cid = {I:(DE-Juel1)IEK-12-20141217},
pnm = {122 - Elektrochemische Energiespeicherung (POF4-122)},
pid = {G:(DE-HGF)POF4-122},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000616816100001},
doi = {10.1002/batt.202100018},
url = {https://juser.fz-juelich.de/record/890729},
}