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@ARTICLE{Kotov:891495,
      author       = {Kotov, Vladislav},
      title        = {{T}wo-modes model of the non-equilibrium plasma chemical
                      dissociation of {CO} 2},
      journal      = {Plasma sources science and technology},
      volume       = {30},
      number       = {5},
      issn         = {0963-0252},
      address      = {Bristol},
      publisher    = {IOP Publ.},
      reportid     = {FZJ-2021-01561},
      pages        = {055003 -},
      year         = {2021},
      abstract     = {The vibrational kinetics model of the dissociation process
                      CO2 + M → CO + O + M based on the two-modes
                      (symmetric-asymmetric) approximation is presented. The model
                      has shown to produce the effective dissociation rate of CO2
                      under conditions of thermal equilibrium close to that
                      obtained experimentally. Results of the 0D calculations of
                      the CO2 conversion in non-equilibrium conditions of a
                      microwave plasma discharge are discussed. The chemical
                      energy efficiency obtained in the calculations at
                      translational-rotational temperature 300 K and degree of
                      ionization 10-5 is between 42 and 56 $\%$ depending on the
                      assumptions. The efficiency is found to reduce and
                      eventually vanish at elevated temperatures.},
      cin          = {IEK-4},
      ddc          = {530},
      cid          = {I:(DE-Juel1)IEK-4-20101013},
      pnm          = {123 - Chemische Energieträger (POF4-123)},
      pid          = {G:(DE-HGF)POF4-123},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:000648719000001},
      doi          = {10.1088/1361-6595/abf368},
      url          = {https://juser.fz-juelich.de/record/891495},
}