% IMPORTANT: The following is UTF-8 encoded. This means that in the presence
% of non-ASCII characters, it will not work with BibTeX 0.99 or older.
% Instead, you should use an up-to-date BibTeX implementation like “bibtex8” or
% “biber”.
@ARTICLE{Reiser:891761,
author = {Reiser, D. and von Keudell, A. and Urbanietz, T.},
title = {{D}etermining {C}hemical {R}eaction {S}ystems in
{P}lasma-{A}ssisted {C}onversion of {M}ethane {U}sing
{G}enetic {A}lgorithms},
journal = {Plasma chemistry and plasma processing},
volume = {41},
issn = {1572-8986},
address = {Dordrecht},
publisher = {Springer Science + Business Media B.V.},
reportid = {FZJ-2021-01721},
pages = {793–813},
year = {2021},
abstract = {Even for processes with only a few gas species involved the
detailed description of plasma-assisted conversion processes
in gas mixtures requires a large amount of processes to be
taken into account and a large number of neutral and charged
particles must be considered. In addition, setting up the
corresponding reaction kinetics model needs the knowledge of
the rate coefficients and their temperature dependence for
all possible reactions between those species. Reduced
reaction networks offer a simplified and pragmatic way to
obtain an overall reaction kinetics model, already useful
for the analysis of experimental data even if not all
details of chemistry can be covered. In this paper we
present a derivation of a data driven reduced model for
plasma-assisted conversion of methane in an helium
environment. By consideration of a small number of
elementary reactions, a simple model is set up. Experimental
data are analyzed by a genetic algorithm that provides
best-fit approximations for the open parameters of the
model. In a further step non-relevant parameters of the
model are identified and a further model reduction is
achieved. The data driven analysis of methane conversion
serves as an illustrative example of the proposed method.
The parameters and reaction channels found are compared with
known results from the literature. The method is described
in detail. The main goal of this work is to present the
potential of this data driven method for a simplified and
pragmatic modeling in the increasingly important field of
plasma-assisted catalytic processes.},
cin = {IEK-4},
ddc = {540},
cid = {I:(DE-Juel1)IEK-4-20101013},
pnm = {123 - Chemische Energieträger (POF4-123)},
pid = {G:(DE-HGF)POF4-123},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000629560500001},
doi = {10.1007/s11090-021-10159-6},
url = {https://juser.fz-juelich.de/record/891761},
}