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@ARTICLE{Khler:891904,
author = {Köhler, Malte and Pomaska, Manuel and Procel, Paul and
Santbergen, Rudi and Zamchiy, Alexandr and Macco, Bart and
Lambertz, Andreas and Duan, Weiyuan and Cao, Pengfei and
Klingebiel, Benjamin and Li, Shenghao and Eberst, Alexander
and Luysberg, Martina and Qiu, Kaifu and Isabella, Olindo
and Finger, Friedhelm and Kirchartz, Thomas and Rau, Uwe and
Ding, Kaining},
title = {{A} silicon carbide-based highly transparent passivating
contact for crystalline silicon solar cells approaching
efficiencies of $24\%$},
journal = {Nature energy},
volume = {6},
issn = {2058-7546},
address = {London},
publisher = {Nature Publishing Group},
reportid = {FZJ-2021-01816},
pages = {529–537},
year = {2021},
abstract = {A highly transparent passivating contact (TPC) as front
contact for crystalline silicon (c-Si) solar cells could in
principle combine high conductivity, excellent surface
passivation and high optical transparency. However, the
simultaneous optimization of these features remains
challenging. Here, we present a TPC consisting of a
silicon-oxide tunnel layer followed by two layers of
hydrogenated nanocrystalline silicon carbide (nc-SiC:H(n))
deposited at different temperatures and a sputtered indium
tin oxide (ITO) layer (c-Si(n)/SiO2/nc-SiC:H(n)/ITO). While
the wide band gap of nc-SiC:H(n) ensures high optical
transparency, the double layer design enables good
passivation and high conductivity translating into an
improved short-circuit current density
(40.87 mA cm−2), fill factor $(80.9\%)$ and efficiency
of $23.99 ± 0.29\%$ (certified). Additionally, this
contact avoids the need for additional hydrogenation or
high-temperature postdeposition annealing steps. We
investigate the passivation mechanism and working principle
of the TPC and provide a loss analysis based on numerical
simulations outlining pathways towards conversion
efficiencies of $26\%.$},
cin = {ER-C-1 / IEK-5},
ddc = {330},
cid = {I:(DE-Juel1)ER-C-1-20170209 / I:(DE-Juel1)IEK-5-20101013},
pnm = {535 - Materials Information Discovery (POF4-535)},
pid = {G:(DE-HGF)POF4-535},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000640742200001},
doi = {10.1038/s41560-021-00806-9},
url = {https://juser.fz-juelich.de/record/891904},
}