TY  - JOUR
AU  - Cojocariu, Iulia
AU  - Feyersinger, Florian
AU  - Puschnig, Peter
AU  - Schio, Luca
AU  - Floreano, Luca
AU  - Feyer, Vitaliy
AU  - Schneider, Claus M.
TI  - Insight into intramolecular chemical structure modifications by on-surface reaction using photoemission tomography
JO  - Chemical communications
VL  - 57
IS  - 24
SN  - 1364-548X
CY  - Cambridge
PB  - Soc.
M1  - FZJ-2021-01844
SP  - 3050 - 3053
PY  - 2021
AB  - The sensitivity of photoemission tomography (PT) to directly probe single molecule on-surface intramolecular reactions will be shown here. PT application in the study of molecules possessing peripheral ligands and structural flexibility is tested on the temperature-induced dehydrogenation intramolecular reaction on Ag(100), leading from CoOEP to the final product CoTBP. Along with the ring-closure reaction, the electronic occupancy and energy level alignment of the frontier orbitals, as well as the oxidation state of the metal ion, are elucidated for both the CoOEP and CoTBP systems.
LB  - PUB:(DE-HGF)16
C6  - 33625406
UR  - <Go to ISI:>//WOS:000631568300016
DO  - DOI:10.1039/D1CC00311A
UR  - https://juser.fz-juelich.de/record/891948
ER  -