Journal Article

FZJ-2021-01844

http://join2-wiki.gsi.de/foswiki/pub/Main/Artwork/join2_logo100x88.png Insight into intramolecular chemical structure modifications by on-surface reaction using photoemission tomography

Cojocariu, I. (Corresponding author)FZJ* ; Feyersinger, F. ; Puschnig, P. ; Schio, L. ; Floreano, L. ; Feyer, V. (Corresponding author)FZJ* ; Schneider, C. M.FZJ*

2021
Soc. Cambridge

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Please use a persistent id in citations: http://hdl.handle.net/2128/27662  doi:10.1039/D1CC00311A

Abstract: The sensitivity of photoemission tomography (PT) to directly probe single molecule on-surface intramolecular reactions will be shown here. PT application in the study of molecules possessing peripheral ligands and structural flexibility is tested on the temperature-induced dehydrogenation intramolecular reaction on Ag(100), leading from CoOEP to the final product CoTBP. Along with the ring-closure reaction, the electronic occupancy and energy level alignment of the frontier orbitals, as well as the oxidation state of the metal ion, are elucidated for both the CoOEP and CoTBP systems.

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Contributing Institute(s):

1. Elektronische Eigenschaften (PGI-6)

Research Program(s):

1. 522 - Quantum Computing (POF4-522) (POF4-522)

Appears in the scientific report 2021

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Database coverage:
; ; ; Allianz-Lizenz / DFG ; Chemical Reactions ; Clarivate Analytics Master Journal List ; Current Contents - Physical, Chemical and Earth Sciences ; Ebsco Academic Search ; Essential Science Indicators ; IF >= 5 ; Index Chemicus ; JCR ; National-Konsortium ; Nationallizenz ; SCOPUS ; Science Citation Index Expanded ; Web of Science Core Collection

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