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000897253 1001_ $$0P:(DE-Juel1)174488$$aMontiel Guerrero, Saul Said$$b0
000897253 245__ $$aImproved Electrochemical Performance of Zinc Anodes by EDTA in Near‐Neutral Zinc−Air Batteries
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000897253 520__ $$aThe influence of ethylenediaminetetraacetic acid (EDTA) electrolyte additive on the performance of Zn−air batteries with near-neutral chloride-based electrolytes was examined for primary and secondary batteries. The electrochemical measurements indicated that Zn is not completely active in neat 2 M NaCl, but still could be discharged up to 1 mA cm−2 around −1.0 VAg/AgCl. The characterization of the Zn surfaces revealed the existence of a passive film consisting of Simonkolleite, Zn(OH)2, and/or ZnO. The EDTA additive enhanced the discharge voltages by 200 mV to −1.2 VAg/AgCl indicating an active Zn surface. The effect of EDTA is explained by its chelation abilities with Zn2+ before formation of hydroxide or oxide species. The Zn−air cells with EDTA were operated up to 930 h with specific energies up to 840 Wh kgZn−1. The cells could also be cycled up to 70 cycles while providing enhanced discharge voltages at 1.15 V over 50 cycles. The positive effect of EDTA is dependent on the amount of free EDTA molecules. Nevertheless, the Zn−air cells showed better performance in terms of higher discharge voltage, discharge energies, and lower overpotentials in presence of EDTA.
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000897253 7001_ $$0P:(DE-Juel1)162243$$aDurmus, Yasin Emre$$b1$$eCorresponding author
000897253 7001_ $$0P:(DE-Juel1)164430$$aDzieciol, Krzysztof$$b2$$ufzj
000897253 7001_ $$0P:(DE-Juel1)180432$$aBasak, Shibabrata$$b3
000897253 7001_ $$0P:(DE-Juel1)161208$$aTempel, Hermann$$b4
000897253 7001_ $$0P:(DE-Juel1)142562$$aWaasen, Stefan$$b5
000897253 7001_ $$0P:(DE-Juel1)157700$$aKungl, Hans$$b6
000897253 7001_ $$0P:(DE-Juel1)156123$$aEichel, Rüdiger-A.$$b7
000897253 773__ $$0PERI:(DE-600)2897248-X$$a10.1002/batt.202100116$$gp. batt.202100116$$n12$$p1830-1842$$tBatteries & supercaps$$v4$$x2566-6223$$y2021
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