% IMPORTANT: The following is UTF-8 encoded.  This means that in the presence
% of non-ASCII characters, it will not work with BibTeX 0.99 or older.
% Instead, you should use an up-to-date BibTeX implementation like “bibtex8” or
% “biber”.

@ARTICLE{MontielGuerrero:897253,
      author       = {Montiel Guerrero, Saul Said and Durmus, Yasin Emre and
                      Dzieciol, Krzysztof and Basak, Shibabrata and Tempel,
                      Hermann and Waasen, Stefan and Kungl, Hans and Eichel,
                      Rüdiger-A.},
      title        = {{I}mproved {E}lectrochemical {P}erformance of {Z}inc
                      {A}nodes by {EDTA} in {N}ear‐{N}eutral {Z}inc−{A}ir
                      {B}atteries},
      journal      = {Batteries $\&$ supercaps},
      volume       = {4},
      number       = {12},
      issn         = {2566-6223},
      address      = {Weinheim},
      publisher    = {Wiley-VCH},
      reportid     = {FZJ-2021-03715},
      pages        = {1830-1842},
      year         = {2021},
      abstract     = {The influence of ethylenediaminetetraacetic acid (EDTA)
                      electrolyte additive on the performance of Zn−air
                      batteries with near-neutral chloride-based electrolytes was
                      examined for primary and secondary batteries. The
                      electrochemical measurements indicated that Zn is not
                      completely active in neat 2 M NaCl, but still could be
                      discharged up to 1 mA cm−2 around −1.0 VAg/AgCl.
                      The characterization of the Zn surfaces revealed the
                      existence of a passive film consisting of Simonkolleite,
                      Zn(OH)2, and/or ZnO. The EDTA additive enhanced the
                      discharge voltages by 200 mV to −1.2 VAg/AgCl
                      indicating an active Zn surface. The effect of EDTA is
                      explained by its chelation abilities with Zn2+ before
                      formation of hydroxide or oxide species. The Zn−air cells
                      with EDTA were operated up to 930 h with specific energies
                      up to 840 Wh kgZn−1. The cells could also be cycled up
                      to 70 cycles while providing enhanced discharge voltages
                      at 1.15 V over 50 cycles. The positive effect of EDTA is
                      dependent on the amount of free EDTA molecules.
                      Nevertheless, the Zn−air cells showed better performance
                      in terms of higher discharge voltage, discharge energies,
                      and lower overpotentials in presence of EDTA.},
      cin          = {IEK-9 / ZEA-2},
      ddc          = {620},
      cid          = {I:(DE-Juel1)IEK-9-20110218 / I:(DE-Juel1)ZEA-2-20090406},
      pnm          = {1223 - Batteries in Application (POF4-122)},
      pid          = {G:(DE-HGF)POF4-1223},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:000681759200001},
      doi          = {10.1002/batt.202100116},
      url          = {https://juser.fz-juelich.de/record/897253},
}