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@ARTICLE{Li:897320,
author = {Li, Shenghao and Pomaska, Manuel and Lambertz, Andreas and
Duan, Weiyuan and Bittkau, Karsten and Qiu, Depeng and Yao,
Zhirong and Luysberg, Martina and Steuter, Paul and Köhler,
Malte and Qiu, Kaifu and Hong, Ruijiang and Shen, Hui and
Finger, Friedhelm and Kirchartz, Thomas and Rau, Uwe and
Ding, Kaining},
title = {{T}ransparent-conductive-oxide-free front contacts for
high-efficiency silicon heterojunction solar cells},
journal = {Joule},
volume = {5},
number = {6},
issn = {2542-4351},
address = {[Cambridge, Mass.]},
publisher = {Cell Press},
reportid = {FZJ-2021-03729},
pages = {1535 - 1547},
year = {2021},
abstract = {In order to compensate the insufficient conductance of
heterojunction thin films, transparent conductive oxides
(TCO) have been used for decades in both sides of contacted
crystalline silicon heterojunction (SHJ) solar cells to
provide lateral conduction for carrier collection. In this
work, we substitute the TCO layers by utilizing the lateral
conduction of c-Si absorber, thereby enabling a TCO-free
design for SHJ solar cells achieving a low series
resistivity of 0.32 Ucm2 and a good fill factor of $80.7\%$
with a conventional finger pitch of 1.8 mm. Achieving high
efficiencies in TCO-free SHJ solar cells requires
suppressing deterioration of the passivation quality induced
by the direct metal-to-a-Si:H contacts. We show that an
ozone treatment at the a-Si:H/metal interface suppresses the
metal diffusion into the a-Si:H layer and improves the
passivation without increasing the contact resistivity. SHJ
solar cells with TCO-free front contacts and ozone treatment
achieve efficiencies of $>22\%.$},
cin = {IEK-5},
ddc = {333.7},
cid = {I:(DE-Juel1)IEK-5-20101013},
pnm = {1213 - Cell Design and Development (POF4-121) /
Verbundvorhaben: TuKaN - Tunnelkontakte auf N-Typ: für die
Metallisierung mit Siebdruck, Teilvorhaben: Herstellung von
Solarzellen mit passivierendem Tunnelkontakt und
funktionalen Schichten aus katalytischer und
plasmaunterstützter chemischer Gasphasenab (0324198D)},
pid = {G:(DE-HGF)POF4-1213 / G:(BMWi)0324198D},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000663028600018},
doi = {10.1016/j.joule.2021.04.004},
url = {https://juser.fz-juelich.de/record/897320},
}