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@ARTICLE{Xia:904012,
      author       = {Xia, Rui and Zhao, Kangning and Kuo, Liang-Yin and Zhang,
                      Lei and Cunha, Daniel M. and Wang, Yang and Huang, Sizhao
                      and Zheng, Jie and Boukamp, Bernard and Kaghazchi, Payam and
                      Sun, Congli and ten Elshof, Johan E. and Huijben, Mark},
      title        = {{N}ickel {N}iobate {A}nodes for {H}igh {R}ate
                      {L}ithium‐{I}on {B}atteries},
      journal      = {Advanced energy materials},
      volume       = {12},
      number       = {1},
      issn         = {1614-6832},
      address      = {Weinheim},
      publisher    = {Wiley-VCH},
      reportid     = {FZJ-2021-05582},
      pages        = {2102972 -},
      year         = {2022},
      abstract     = {Fast charging is one of the key requirements for
                      next-generation lithium-ion batteries, however, lithium-ion
                      diffusion rates of typical electrode materials are limited.
                      Nanosizing of active electrode material is a common strategy
                      to increase the effective lithium-ion diffusion transport
                      rate, but it also decreases the volumetric energy/power
                      density and stability of the battery. In this work, nickel
                      niobate NiNb2O6 is demonstrated for the first time as a new
                      intrinsic high-rate anode material for lithium-ion batteries
                      without the requirement of realizing nano-architectures. The
                      NiNb2O6 host crystal structure exhibits only a single type
                      of channel for lithium-ion intercalation and can be fully
                      lithiated with a capacity of about 244 mAh g−1 at low
                      current densities. Interestingly, a high diffusion
                      coefficient of 10−12 cm2 s−1 at 300 K enables fast
                      (dis)charging at high current densities resulting in high
                      capacities of 140 and 50 mAh g−1 for 10 and 100C
                      respectively. The minimal volume change during lithiation is
                      the origin of the stable reversible lithiation process in
                      NiNb2O6 and leads to $81\%$ capacity retention after
                      20 000 cycles at 100C. Finally, full cell systems against
                      LiFePO4 and Li[Ni0.8Co0.1Mn0.1]O2 (NCM811) cathodes
                      demonstrate the promising energy storage performance of
                      nickel niobate anodes in practical battery devices.},
      cin          = {IEK-1},
      ddc          = {050},
      cid          = {I:(DE-Juel1)IEK-1-20101013},
      pnm          = {1221 - Fundamentals and Materials (POF4-122)},
      pid          = {G:(DE-HGF)POF4-1221},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:000718209700001},
      doi          = {10.1002/aenm.202102972},
      url          = {https://juser.fz-juelich.de/record/904012},
}