Journal Article

FZJ-2021-05582

http://join2-wiki.gsi.de/foswiki/pub/Main/Artwork/join2_logo100x88.png Nickel Niobate Anodes for High Rate Lithium‐Ion Batteries

Xia, R. ; Zhao, K. ; Kuo, L.-Y.FZJ* ; Zhang, L. ; Cunha, D. M. ; Wang, Y. ; Huang, S. ; Zheng, J. ; Boukamp, B. ; Kaghazchi, P. (Corresponding author)FZJ* ; Sun, C. ; ten Elshof, J. E. ; Huijben, M. (Corresponding author)

2022
Wiley-VCH Weinheim

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Please use a persistent id in citations: http://hdl.handle.net/2128/30641  doi:10.1002/aenm.202102972

Abstract: Fast charging is one of the key requirements for next-generation lithium-ion batteries, however, lithium-ion diffusion rates of typical electrode materials are limited. Nanosizing of active electrode material is a common strategy to increase the effective lithium-ion diffusion transport rate, but it also decreases the volumetric energy/power density and stability of the battery. In this work, nickel niobate NiNb2O6 is demonstrated for the first time as a new intrinsic high-rate anode material for lithium-ion batteries without the requirement of realizing nano-architectures. The NiNb2O6 host crystal structure exhibits only a single type of channel for lithium-ion intercalation and can be fully lithiated with a capacity of about 244 mAh g−1 at low current densities. Interestingly, a high diffusion coefficient of 10−12 cm2 s−1 at 300 K enables fast (dis)charging at high current densities resulting in high capacities of 140 and 50 mAh g−1 for 10 and 100C respectively. The minimal volume change during lithiation is the origin of the stable reversible lithiation process in NiNb2O6 and leads to 81% capacity retention after 20 000 cycles at 100C. Finally, full cell systems against LiFePO4 and Li[Ni0.8Co0.1Mn0.1]O2 (NCM811) cathodes demonstrate the promising energy storage performance of nickel niobate anodes in practical battery devices.

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Contributing Institute(s):

1. Werkstoffsynthese und Herstellungsverfahren (IEK-1)

Research Program(s):

1. 1221 - Fundamentals and Materials (POF4-122) (POF4-122)

Appears in the scientific report 2022

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Database coverage:
; ; ; Clarivate Analytics Master Journal List ; Current Contents - Engineering, Computing and Technology ; Current Contents - Physical, Chemical and Earth Sciences ; DEAL Wiley ; Ebsco Academic Search ; Essential Science Indicators ; IF >= 25 ; JCR ; SCOPUS ; Science Citation Index Expanded ; Web of Science Core Collection

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