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@ARTICLE{Ariantari:904303,
      author       = {Ariantari, Ni Putu and Frank, Marian and Gao, Ying and
                      Stuhldreier, Fabian and Kiffe-Delf, Anna-Lene and Hartmann,
                      Rudolf and Höfert, Simon-Patrick and Janiak, Christoph and
                      Wesselborg, Sebastian and Müller, Werner E. G. and
                      Kalscheuer, Rainer and Liu, Zhen and Proksch, Peter},
      title        = {{F}usaristatins {D}–{F} and
                      (7{S},8{R})-(−)-chlamydospordiol from {F}usarium sp.
                      {BZCB}-{CA}, an endophyte of {B}othriospermum chinense},
      journal      = {Tetrahedron},
      volume       = {85},
      issn         = {0040-4020},
      address      = {Amsterdam [u.a.]},
      publisher    = {Elsevier Science},
      reportid     = {FZJ-2021-05873},
      pages        = {132065 -},
      year         = {2021},
      note         = {Kein Post-print vorhanden},
      abstract     = {Three new lipodepsipeptides, fusaristatins DeF ( 1e3) and a
                      new a-pyrone derivative, (7S,8R)-()-chlamydospordiol (5),
                      together with eight known compounds (4, 6e12) were obtained
                      from solidrice cultures of Fusarium sp. BZCB-CA, an
                      endophyte of the Chinese medicinal plant,
                      Bothriospermumchinense. The planar structures of the new
                      metabolites (1e3, 5) were established by
                      spectroscopictechniques (1D/2D NMR and HRESIMS). Marfey’s
                      method was applied to determine the absoluteconfiguration of
                      1, while the absolute configuration of 5 was determined by
                      single-crystal X-ray crys-tallography analysis in addition
                      to Mosher’s method. Crystallographic data of inflatin C
                      (7) are alsosupplied here for the first time. In
                      cytotoxicity assays, rubrofusarin (8) showed a moderate
                      effect on thelymphoma cell lines L5178Y, Ramos and Jurkat,
                      with IC50 values of 7.7, 6.2 and 6.3 mM, respectively,
                      whilethe remaining compounds were inactive. When subjected
                      to antibacterial assay, only lateropyrone (9)exhibited good
                      to weak activity against a panel of Gram-positive bacteria
                      including drug-resistant strainswith MICs ranging from 3.1
                      to 25 mM.},
      cin          = {IBI-7},
      ddc          = {540},
      cid          = {I:(DE-Juel1)IBI-7-20200312},
      pnm          = {5244 - Information Processing in Neuronal Networks
                      (POF4-524)},
      pid          = {G:(DE-HGF)POF4-5244},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:000634925100023},
      doi          = {10.1016/j.tet.2021.132065},
      url          = {https://juser.fz-juelich.de/record/904303},
}