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@ARTICLE{Nilsson:904792,
author = {Nilsson, Daniel and Bozorg, Behruz and Mohanty, Sandipan
and Söderberg, Bo and Irbäck, Anders},
title = {{L}imitations of field-theory simulation for exploring
phase separation: {T}he role of repulsion in a lattice
protein model},
journal = {The journal of chemical physics},
volume = {156},
number = {1},
issn = {0021-9606},
address = {Melville, NY},
publisher = {American Institute of Physics},
reportid = {FZJ-2022-00122},
pages = {015101 -},
year = {2022},
abstract = {Field-theory simulation by the complex Langevin method
offers an alternative to conventional sampling techniques
for exploring the forces driving biomolecular liquid-liquid
phase separation. Such simulations have recently been used
to study several polyampholyte systems. Here, we formulate a
field theory corresponding to the hydrophobic/polar HP
lattice protein model, with finite same-site repulsion and
nearest-neighbor attraction between HH bead pairs. By direct
comparison with particle-based Monte Carlo simulations, we
show that complex Langevin sampling of the field theory
reproduces the thermodynamic properties of the HP model only
if the same-site repulsion is not too strong. Unfortunately,
the repulsion has to be taken weaker than what is needed to
prevent condensed droplets from assuming an artificially
compact shape. Analysis of a minimal and analytically
solvable toy model hints that the sampling problems caused
by repulsive interaction may stem from a loss of
ergodicity.},
cin = {JSC},
ddc = {530},
cid = {I:(DE-Juel1)JSC-20090406},
pnm = {5111 - Domain-Specific Simulation $\&$ Data Life Cycle Labs
(SDLs) and Research Groups (POF4-511)},
pid = {G:(DE-HGF)POF4-5111},
typ = {PUB:(DE-HGF)16},
pubmed = {34998327},
UT = {WOS:000739267900004},
doi = {10.1063/5.0070412},
url = {https://juser.fz-juelich.de/record/904792},
}