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@ARTICLE{Na:905805,
author = {Na, Youngseung and Khadke, Prashant and Glüsen, Andreas
and Kimiaie, Nicola and Müller, Martin and Krewer, Ulrike},
title = {{A} robust methanol concentration sensing technique in
direct methanol fuel cells and stacks using cell dynamics},
journal = {International journal of hydrogen energy},
volume = {47},
number = {9},
issn = {0360-3199},
address = {New York, NY [u.a.]},
publisher = {Elsevier},
reportid = {FZJ-2022-01025},
pages = {6237-6246},
year = {2022},
abstract = {The electrochemical behaviour of direct methanol fuel cells
(DMFCs) is sensitive to methanol concentration; thus, to
avoid external sensors, it is a promising candidate to
monitor the concentration of methanol in the fuel
circulation loop, which is central to the efficient
operation of direct methanol fuel cell systems. We address
this issue and report on an extremely robust electrochemical
methanol sensing technique that is not sensitive to
temperature, cell degradation and membrane electrode
assembly (MEA) type. We develop a temperature independent
empirical correlation of the dynamic response of cell
voltage to step changes in current with methanol
concentration. This equation is successfully validated under
various operating scenarios at both the single cell and
stack levels. Our sensing method achieves an impressive
accuracy of ±0.1 M and this is expected to increase the
reliability of methanol sensing and simplify the control
logic of DMFC systems.},
cin = {IEK-14},
ddc = {620},
cid = {I:(DE-Juel1)IEK-14-20191129},
pnm = {1231 - Electrochemistry for Hydrogen (POF4-123)},
pid = {G:(DE-HGF)POF4-1231},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000749265100002},
doi = {10.1016/j.ijhydene.2021.11.249},
url = {https://juser.fz-juelich.de/record/905805},
}