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@ARTICLE{Sondermann:906317,
author = {Sondermann, Linda and Jiang, Wulv and Shviro, Meital and
Spieß, Alex and Woschko, Dennis and Rademacher, Lars and
Janiak, Christoph},
title = {{N}ickel-{B}ased {M}etal-{O}rganic {F}rameworks as
{E}lectrocatalysts for the {O}xygen {E}volution {R}eaction
({OER})},
journal = {Molecules},
volume = {27},
number = {4},
issn = {1420-3049},
address = {Basel},
publisher = {MDPI},
reportid = {FZJ-2022-01367},
pages = {1241 -},
year = {2022},
abstract = {The exploration of earth-abundant electrocatalysts with
high performance for the oxygen evolution reaction (OER) is
eminently desirable and remains a significant challenge. The
composite of the metal-organic framework (MOF) Ni10Co-BTC
(BTC = 1,3,5-benzenetricarboxylate) and the highly
conductive carbon material ketjenblack (KB) could be easily
obtained from the MOF synthesis in the presence of KB in a
one-step solvothermal reaction. The composite and the
pristine MOF perform better than commercially available
Ni/NiO nanoparticles under the same conditions for the OER.
Activation of the nickel-cobalt clusters from the MOF can be
seen under the applied anodic potential, which steadily
boosts the OER performance. Ni10Co-BTC and Ni10Co-BTC/KB are
used as sacrificial agents and undergo structural changes
during electrochemical measurements, the stabilized
materials show good OER performances.},
cin = {IEK-14},
ddc = {540},
cid = {I:(DE-Juel1)IEK-14-20191129},
pnm = {1231 - Electrochemistry for Hydrogen (POF4-123)},
pid = {G:(DE-HGF)POF4-1231},
typ = {PUB:(DE-HGF)16},
pubmed = {35209029},
UT = {WOS:000764424600001},
doi = {10.3390/molecules27041241},
url = {https://juser.fz-juelich.de/record/906317},
}