guest ::
| Home > Publications database > Improved Capacity Retention for a Disordered Rocksalt Cathode via Solvate Ionic Liquid Electrolytes > print |
| Home > Publications database > Improved Capacity Retention for a Disordered Rocksalt Cathode via Solvate Ionic Liquid Electrolytes > print |
| 001 | 907419 | ||
| 005 | 20240712113103.0 | ||
| 024 | 7 | _ | |a 10.1002/batt.202200075 |2 doi |
| 024 | 7 | _ | |a 2128/31569 |2 Handle |
| 024 | 7 | _ | |a altmetric:126409173 |2 altmetric |
| 024 | 7 | _ | |a WOS:000787102500001 |2 WOS |
| 037 | _ | _ | |a FZJ-2022-02027 |
| 082 | _ | _ | |a 620 |
| 100 | 1 | _ | |a Wichmann, Lennart |0 P:(DE-Juel1)187473 |b 0 |u fzj |
| 245 | _ | _ | |a Improved Capacity Retention for a Disordered Rocksalt Cathode via Solvate Ionic Liquid Electrolytes |
| 260 | _ | _ | |a Weinheim |c 2022 |b Wiley-VCH |
| 336 | 7 | _ | |a article |2 DRIVER |
| 336 | 7 | _ | |a Output Types/Journal article |2 DataCite |
| 336 | 7 | _ | |a Journal Article |b journal |m journal |0 PUB:(DE-HGF)16 |s 1658906549_11504 |2 PUB:(DE-HGF) |
| 336 | 7 | _ | |a ARTICLE |2 BibTeX |
| 336 | 7 | _ | |a JOURNAL_ARTICLE |2 ORCID |
| 336 | 7 | _ | |a Journal Article |0 0 |2 EndNote |
| 520 | _ | _ | |a Lithium-rich disordered rocksalts (DRX) are a promising class of cathode materials for high-energy lithium ion batteries (LIBs) and lithium metal batteries (LMBs) due to the high initial specific capacities (>200 mAh g−1) as well as flexible chemical composition. However, challenges concerning severe capacity fade and voltage decay upon cycling at high cut-off voltages are still to be overcome. Moreover, state-of-the-art carbonate-based electrolytes can be decomposed by reactive oxygen species released by DRX materials during cycling. In this work, the electrochemical performance of Li1.25Fe0.5Nb0.25O2 (LFNO) || Li LMB and LFNO || graphite LIB cells is compared for a conventional, carbonate-based electrolyte and the solvate ionic liquid (SIL) [Li(G3)][TFSI] (G3: triethyleneglycoldimethylether). Cycle life is notably improved by the chemically more stable ionic liquid electrolyte, as the anionic redox activity of LFNO is prolonged compared to the carbonate-based cells. This work represents an important step toward an improved cycle life of DRX cathodes. |
| 536 | _ | _ | |a 1221 - Fundamentals and Materials (POF4-122) |0 G:(DE-HGF)POF4-1221 |c POF4-122 |f POF IV |x 0 |
| 588 | _ | _ | |a Dataset connected to CrossRef, Journals: juser.fz-juelich.de |
| 700 | 1 | _ | |a Brinkmann, Jan-Paul |0 P:(DE-Juel1)176761 |b 1 |u fzj |
| 700 | 1 | _ | |a Luo, Mingzeng |0 P:(DE-HGF)0 |b 2 |
| 700 | 1 | _ | |a Yang, Yong |0 0000-0002-9928-7165 |b 3 |
| 700 | 1 | _ | |a Winter, Martin |0 P:(DE-Juel1)166130 |b 4 |
| 700 | 1 | _ | |a Schmuch, Richard |0 0000-0002-5670-0327 |b 5 |
| 700 | 1 | _ | |a Placke, Tobias |0 0000-0002-2097-5193 |b 6 |e Corresponding author |
| 700 | 1 | _ | |a Gomez-Martin, Aurora |0 0000-0001-7053-3986 |b 7 |e Corresponding author |
| 773 | _ | _ | |a 10.1002/batt.202200075 |0 PERI:(DE-600)2897248-X |n 7 |p e202200075 |t Batteries & supercaps |v 5 |y 2022 |x 2566-6223 |
| 856 | 4 | _ | |y OpenAccess |u https://juser.fz-juelich.de/record/907419/files/Batteries%20Supercaps%20-%202022%20-%20Wichmann%20-%20Improved%20Capacity%20Retention%20for%20a%20Disordered%20Rocksalt%20Cathode%20via%20Solvate%20Ionic.pdf |
| 856 | 4 | _ | |y OpenAccess |u https://juser.fz-juelich.de/record/907419/files/GetFileAttachment_Improved.pdf |
| 909 | C | O | |o oai:juser.fz-juelich.de:907419 |p openaire |p open_access |p VDB |p driver |p dnbdelivery |
| 910 | 1 | _ | |a Forschungszentrum Jülich |0 I:(DE-588b)5008462-8 |k FZJ |b 0 |6 P:(DE-Juel1)187473 |
| 910 | 1 | _ | |a Forschungszentrum Jülich |0 I:(DE-588b)5008462-8 |k FZJ |b 1 |6 P:(DE-Juel1)176761 |
| 910 | 1 | _ | |a Forschungszentrum Jülich |0 I:(DE-588b)5008462-8 |k FZJ |b 4 |6 P:(DE-Juel1)166130 |
| 913 | 1 | _ | |a DE-HGF |b Forschungsbereich Energie |l Materialien und Technologien für die Energiewende (MTET) |1 G:(DE-HGF)POF4-120 |0 G:(DE-HGF)POF4-122 |3 G:(DE-HGF)POF4 |2 G:(DE-HGF)POF4-100 |4 G:(DE-HGF)POF |v Elektrochemische Energiespeicherung |9 G:(DE-HGF)POF4-1221 |x 0 |
| 914 | 1 | _ | |y 2022 |
| 915 | _ | _ | |a Creative Commons Attribution CC BY 4.0 |0 LIC:(DE-HGF)CCBY4 |2 HGFVOC |
| 915 | _ | _ | |a DEAL Wiley |0 StatID:(DE-HGF)3001 |2 StatID |d 2020-08-32 |w ger |
| 915 | _ | _ | |a WoS |0 StatID:(DE-HGF)0113 |2 StatID |b Science Citation Index Expanded |d 2020-08-32 |
| 915 | _ | _ | |a OpenAccess |0 StatID:(DE-HGF)0510 |2 StatID |
| 915 | _ | _ | |a DBCoverage |0 StatID:(DE-HGF)0160 |2 StatID |b Essential Science Indicators |d 2020-08-32 |
| 915 | _ | _ | |a DBCoverage |0 StatID:(DE-HGF)0200 |2 StatID |b SCOPUS |d 2022-11-23 |
| 915 | _ | _ | |a DBCoverage |0 StatID:(DE-HGF)0300 |2 StatID |b Medline |d 2022-11-23 |
| 915 | _ | _ | |a DBCoverage |0 StatID:(DE-HGF)0199 |2 StatID |b Clarivate Analytics Master Journal List |d 2022-11-23 |
| 915 | _ | _ | |a DBCoverage |0 StatID:(DE-HGF)0150 |2 StatID |b Web of Science Core Collection |d 2022-11-23 |
| 915 | _ | _ | |a DBCoverage |0 StatID:(DE-HGF)1150 |2 StatID |b Current Contents - Physical, Chemical and Earth Sciences |d 2022-11-23 |
| 920 | 1 | _ | |0 I:(DE-Juel1)IEK-12-20141217 |k IEK-12 |l Helmholtz-Institut Münster Ionenleiter für Energiespeicher |x 0 |
| 980 | 1 | _ | |a FullTexts |
| 980 | _ | _ | |a journal |
| 980 | _ | _ | |a VDB |
| 980 | _ | _ | |a UNRESTRICTED |
| 980 | _ | _ | |a I:(DE-Juel1)IEK-12-20141217 |
| 981 | _ | _ | |a I:(DE-Juel1)IMD-4-20141217 |
| Library | Collection | CLSMajor | CLSMinor | Language | Author |
|---|