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| 100 | 1 | _ | |a Solymosi, Thomas |0 P:(DE-Juel1)180742 |b 0 |
| 245 | _ | _ | |a Nucleation as a rate-determining step in catalytic gas generation reactions from liquid phase systems |
| 260 | _ | _ | |a Washington, DC [u.a.] |c 2022 |b Assoc. |
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| 520 | _ | _ | |a The observable reaction rate of heterogeneously catalyzed reactions is known to be limited either by the intrinsic kinetics of the catalytic transformation or by the rate of pore and/or film diffusion. Here, we show that in gas generation reactions from liquid reactants, the nucleation of gas bubbles in the catalyst pore structure represents an additional important rate-limiting step. This is highlighted for the example of catalytic hydrogen release from the liquid organic hydrogen carrier compound perhydro-dibenzyltoluene. A nucleation-inhibited catalytic system produces only dissolved hydrogen with fast saturation of the fluid phase around the active site, while bubble formation enhances mass transfer by more than a factor of 50 in an oscillating reaction regime. Nucleation can be efficiently triggered not only by temperature changes and catalyst surface modification but also by a mechanical stimulus. Our work sheds new light on performance-limiting factors in reactions that are of highest relevance for the future green hydrogen economy. |
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| 700 | 1 | _ | |a Wasserscheid, Peter |0 P:(DE-Juel1)162305 |b 12 |e Corresponding author |u fzj |
| 773 | _ | _ | |a 10.1126/sciadv.ade3262 |g Vol. 8, no. 46, p. eade3262 |0 PERI:(DE-600)2810933-8 |n 46 |p eade3262 |t Science advances |v 8 |y 2022 |x 2375-2548 |
| 856 | 4 | _ | |u https://juser.fz-juelich.de/record/910296/files/Invoice_APC600359027.pdf |
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