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@ARTICLE{Overhoff:910716,
      author       = {Overhoff, Gerrit Michael and Ali, Md Yusuf and Brinkmann,
                      Jan-Paul and Lennartz, Peter and Orthner, Hans and Hammad,
                      Mohaned and Wiggers, Hartmut and Winter, Martin and
                      Brunklaus, Gunther},
      title        = {{C}eramic-in-{P}olymer {H}ybrid {E}lectrolytes with
                      {E}nhanced {E}lectrochemical {P}erformance},
      journal      = {ACS applied materials $\&$ interfaces},
      volume       = {14},
      issn         = {1944-8244},
      address      = {Washington, DC},
      publisher    = {Soc.},
      reportid     = {FZJ-2022-04086},
      pages        = {53636−53647},
      year         = {2022},
      abstract     = {Polymer electrolytes are attractive candidates to boost the
                      application of rechargeable lithium metal batteries.
                      Single-ion conducting polymers may reduce polarization and
                      lithium dendrite growth, though these materials could be
                      mechanically overly rigid, thus requiring ion mobilizers
                      such as organic solvents to foster transport of Li ions. An
                      inhomogeneous mobilizer distribution and occurrence of
                      preferential Li transport pathways eventually yield favored
                      spots for Li plating, thereby imposing additional mechanical
                      stress and even premature cell short circuits. In this work,
                      we explored ceramic-in-polymer hybrid electrolytes
                      consisting of polymer blends of single-ion conducting
                      polymer and PVdF-HFP, including EC/PC as swelling agents and
                      silane-functionalized LATP particles. The hybrid electrolyte
                      features an oxide-rich layer that notably stabilizes the
                      interphase toward Li metal, enabling single-side lithium
                      deposition for over 700 h at a current density of 0.1 mA
                      cm–2. The incorporated oxide particles significantly
                      reduce the natural solvent uptake from 140 to 38 wt $\%$
                      despite maintaining reasonably high ionic conductivities.
                      Its electrochemical performance was evaluated in
                      LiNi0.6Co0.2Mn0.2O2 (NMC622)||Li metal cells, exhibiting
                      impressive capacity retention over 300 cycles. Notably, very
                      thin LiNbO3 coating of the cathode material further boosts
                      the cycling stability, resulting in an overall capacity
                      retention of $78\%$ over more than 600 cycles, clearly
                      highlighting the potential of hybrid electrolyte concepts.},
      cin          = {IEK-12},
      ddc          = {600},
      cid          = {I:(DE-Juel1)IEK-12-20141217},
      pnm          = {1223 - Batteries in Application (POF4-122) / 1222 -
                      Components and Cells (POF4-122) / FestBatt-Polymere -
                      Materialplattform 'Polymere' im Rahmen des Kompetenzclusters
                      für Festkörperbatterien (13XP0175A)},
      pid          = {G:(DE-HGF)POF4-1223 / G:(DE-HGF)POF4-1222 /
                      G:(BMBF)13XP0175A},
      typ          = {PUB:(DE-HGF)16},
      pubmed       = {36409931},
      UT           = {WOS:000890332000001},
      doi          = {10.1021/acsami.2c13408},
      url          = {https://juser.fz-juelich.de/record/910716},
}