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@ARTICLE{Koch:916360,
author = {Koch, Vanessa M. and Charvot, Jaroslav and Cao, Yuanyuan
and Hartmann, Claudia and Wilks, Regan G. and Kundrata, Ivan
and Mínguez-Bacho, Ignacio and Gheshlaghi, Negar and Hoga,
Felix and Stubhan, Tobias and Alex, Wiebke and Pokorný,
Daniel and Topraksal, Ece and Smith, Ana-Sunčana and
Brabec, Christoph and Bär, Marcus and Guldi, Dirk M. and
Barr, Maïssa K. S. and Bureš, Filip and Bachmann, Julien},
title = {{S}b 2 {S}e 3 {T}hin-{F}ilm {G}rowth by {S}olution {A}tomic
{L}ayer {D}eposition},
journal = {Chemistry of materials},
volume = {34},
number = {21},
issn = {0897-4756},
address = {Washington, DC},
publisher = {American Chemical Society},
reportid = {FZJ-2022-06161},
pages = {9392 - 9401},
year = {2022},
abstract = {We establish solution atomic layer deposition (sALD) for
the controlled growth of pure Sb2Se3 thin films under mild
conditions, namely, room temperature and atmospheric
pressure. Upscaling this process yields Sb2Se3 thin films
with high homogeneity over large-area (4″) substrates.
Annealing of the initially amorphous material leads to
highly crystalline and smooth Sb2Se3 thin films. Removing
the constraints of thermal stability and sufficient
volatility in sALD compared to traditional gas-phase ALD
opens up a broad choice of precursors and allows us to
examine a wide range of Se2– precursors, of which some
exhibit facile synthetic routes and allow us to tune their
reactivity for optimal experimental ease of use. Moreover,
we demonstrate that the solvent used in sALD represents an
additional, attractive tool to influence and tailor the
reactivity at the liquid–solid interface between the
precursors and the surface.},
cin = {IEK-11},
ddc = {540},
cid = {I:(DE-Juel1)IEK-11-20140314},
pnm = {1212 - Materials and Interfaces (POF4-121)},
pid = {G:(DE-HGF)POF4-1212},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000883769200001},
doi = {10.1021/acs.chemmater.2c01550},
url = {https://juser.fz-juelich.de/record/916360},
}