000916804 001__ 916804
000916804 005__ 20240712113114.0
000916804 0247_ $$2doi$$a10.1039/D2TA02179J
000916804 0247_ $$2ISSN$$a2050-7488
000916804 0247_ $$2ISSN$$a2050-7496
000916804 0247_ $$2Handle$$a2128/34071
000916804 0247_ $$2WOS$$aWOS:000901486000001
000916804 037__ $$aFZJ-2023-00107
000916804 082__ $$a530
000916804 1001_ $$0P:(DE-HGF)0$$aWoolley, Henry M.$$b0
000916804 245__ $$aHybrid solid electrolyte-liquid electrolyte systems for (almost) solid-state batteries: Why, how, and where to?
000916804 260__ $$aLondon ˜[u.a.]œ$$bRSC$$c2023
000916804 3367_ $$2DRIVER$$aarticle
000916804 3367_ $$2DataCite$$aOutput Types/Journal article
000916804 3367_ $$0PUB:(DE-HGF)16$$2PUB:(DE-HGF)$$aJournal Article$$bjournal$$mjournal$$s1677855339_4687
000916804 3367_ $$2BibTeX$$aARTICLE
000916804 3367_ $$2ORCID$$aJOURNAL_ARTICLE
000916804 3367_ $$00$$2EndNote$$aJournal Article
000916804 520__ $$aAll-solid-state batteries (SSBs) offer an alternative to current state of the art lithium-ion batteries, promising improved safety and higher energy densities due to the incorporation of non-flammable solid electrolytes and Li metal as an anode material. Despite this, SSBs face numerous issues, including the tendency for the solid electrolytes to decompose upon contact with anode and cathode materials as well as during cycling. In addition, poor particle on particle contact can result in sluggish transport of lithium ions to and from the solid electrolytes. One potential solution is by combining the solid electrolyte with a liquid electrolyte to form a hybrid solid–liquid electrolyte system. By using a liquid electrolyte with a wide electrochemical stability window and good wetting properties some of the problems with solid electrolytes in SSBs may be overcome. However, due to the reactive nature of solid electrolytes, a new interphase known as the solid liquid electrolyte interphase (SLEI) forms. This SLEI may be resistive and therefore increase the total impedance of the cell, thus making certain liquid/solid electrolyte combinations unsuitable for use in ASSBs. In this review we discuss the recent history of these systems, look into the ionic transport model and focus on how the chemical stability of the solid electrolyte with respect to the liquid electrolyte is a vital factor in the formation of a stable SLEI. In the case of salt-in-solvent systems the stability of the solid electrolyte is driven by the chemical nature of the solvent, therefore we also discuss what solvent properties-such as dielectric constant or donor number-may have an effect on the degree of decomposition of the solid electrolyte used.
000916804 536__ $$0G:(DE-HGF)POF4-1221$$a1221 - Fundamentals and Materials (POF4-122)$$cPOF4-122$$fPOF IV$$x0
000916804 536__ $$0G:(DE-HGF)POF4-1222$$a1222 - Components and Cells (POF4-122)$$cPOF4-122$$fPOF IV$$x1
000916804 588__ $$aDataset connected to CrossRef, Journals: juser.fz-juelich.de
000916804 7001_ $$0P:(DE-Juel1)184936$$aVargas-Barbosa, Nella M.$$b1$$eCorresponding author
000916804 773__ $$0PERI:(DE-600)2702232-8$$a10.1039/D2TA02179J$$gp. 10.1039.D2TA02179J$$n3$$p1083-1097 $$tJournal of materials chemistry / A$$v11$$x2050-7488$$y2023
000916804 8564_ $$uhttps://juser.fz-juelich.de/record/916804/files/Genehmigung_von_Veroeffentlichungen_9975010.pdf
000916804 8564_ $$uhttps://juser.fz-juelich.de/record/916804/files/d2ta02179j.pdf$$yOpenAccess
000916804 8767_ $$d2023-02-15$$eAPC$$jPublish and Read
000916804 909CO $$ooai:juser.fz-juelich.de:916804$$pdnbdelivery$$popenCost$$pVDB$$pdriver$$pOpenAPC$$popen_access$$popenaire
000916804 9101_ $$0I:(DE-588b)5008462-8$$6P:(DE-Juel1)184936$$aForschungszentrum Jülich$$b1$$kFZJ
000916804 9131_ $$0G:(DE-HGF)POF4-122$$1G:(DE-HGF)POF4-120$$2G:(DE-HGF)POF4-100$$3G:(DE-HGF)POF4$$4G:(DE-HGF)POF$$9G:(DE-HGF)POF4-1221$$aDE-HGF$$bForschungsbereich Energie$$lMaterialien und Technologien für die Energiewende (MTET)$$vElektrochemische Energiespeicherung$$x0
000916804 9131_ $$0G:(DE-HGF)POF4-122$$1G:(DE-HGF)POF4-120$$2G:(DE-HGF)POF4-100$$3G:(DE-HGF)POF4$$4G:(DE-HGF)POF$$9G:(DE-HGF)POF4-1222$$aDE-HGF$$bForschungsbereich Energie$$lMaterialien und Technologien für die Energiewende (MTET)$$vElektrochemische Energiespeicherung$$x1
000916804 9141_ $$y2023
000916804 915pc $$0PC:(DE-HGF)0000$$2APC$$aAPC keys set
000916804 915pc $$0PC:(DE-HGF)0001$$2APC$$aLocal Funding
000916804 915pc $$0PC:(DE-HGF)0002$$2APC$$aDFG OA Publikationskosten
000916804 915pc $$0PC:(DE-HGF)0110$$2APC$$aTIB: Royal Society of Chemistry 2021
000916804 915__ $$0LIC:(DE-HGF)CCBY3$$2HGFVOC$$aCreative Commons Attribution CC BY 3.0
000916804 915__ $$0StatID:(DE-HGF)0160$$2StatID$$aDBCoverage$$bEssential Science Indicators$$d2022-11-09
000916804 915__ $$0StatID:(DE-HGF)0113$$2StatID$$aWoS$$bScience Citation Index Expanded$$d2022-11-09
000916804 915__ $$0StatID:(DE-HGF)0510$$2StatID$$aOpenAccess
000916804 915__ $$0StatID:(DE-HGF)0430$$2StatID$$aNational-Konsortium$$d2023-08-23$$wger
000916804 915__ $$0StatID:(DE-HGF)0300$$2StatID$$aDBCoverage$$bMedline$$d2023-08-23
000916804 915__ $$0StatID:(DE-HGF)0199$$2StatID$$aDBCoverage$$bClarivate Analytics Master Journal List$$d2023-08-23
000916804 915__ $$0StatID:(DE-HGF)0150$$2StatID$$aDBCoverage$$bWeb of Science Core Collection$$d2023-08-23
000916804 915__ $$0StatID:(DE-HGF)1160$$2StatID$$aDBCoverage$$bCurrent Contents - Engineering, Computing and Technology$$d2023-08-23
000916804 915__ $$0StatID:(DE-HGF)1150$$2StatID$$aDBCoverage$$bCurrent Contents - Physical, Chemical and Earth Sciences$$d2023-08-23
000916804 915__ $$0StatID:(DE-HGF)0100$$2StatID$$aJCR$$bJ MATER CHEM A : 2022$$d2023-08-23
000916804 915__ $$0StatID:(DE-HGF)0200$$2StatID$$aDBCoverage$$bSCOPUS$$d2023-08-23
000916804 915__ $$0StatID:(DE-HGF)9910$$2StatID$$aIF >= 10$$bJ MATER CHEM A : 2022$$d2023-08-23
000916804 920__ $$lyes
000916804 9201_ $$0I:(DE-Juel1)IEK-12-20141217$$kIEK-12$$lHelmholtz-Institut Münster Ionenleiter für Energiespeicher$$x0
000916804 9801_ $$aAPC
000916804 9801_ $$aFullTexts
000916804 980__ $$ajournal
000916804 980__ $$aVDB
000916804 980__ $$aUNRESTRICTED
000916804 980__ $$aI:(DE-Juel1)IEK-12-20141217
000916804 980__ $$aAPC
000916804 981__ $$aI:(DE-Juel1)IMD-4-20141217