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Structural evolution and physical properties of Bi1-xGdxFeO3 ceramics

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2010
Elsevier Science Amsterdam [u.a.]

Acta materialia 58, 3701 - 3708 () [10.1016/j.actamat.2010.03.007]

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Abstract: The crystal structure and physical properties of Bi1-xGdxFeO3 ceramics with x <= 0.5 have been studied by X-ray diffraction, differential scanning calorimetry, dielectric and magnetic measurements. Bi1-xGdxFeO3 compounds crystallize at room temperature in R3c structure for x < 0.08 and in Pbnin structure for x >= 0.3. The R3c phase transforms to the Pbnm phase as temperature increases. Temperature-dependent dielectric response and low-temperature X-ray diffraction indicate a phase transition of the Pbnm phase at low-temperature. Detailed structural analysis indicates that the interaction between Bi and O plays an important role in the evolution of structure and physical properties. A phase diagram is constructed to illustrate the physical property composition temperature relations. (C) 2010 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.

Keyword(s): J ; Bi-based magnetoelectric perovskites (auto) ; Crystal structure (auto) ; Phase transformation (auto) ; X-ray diffraction (auto)


Note: This work is supported by National Basic Research Program of China (No. 2007CB925003) and National Natural Science Foundation of China (No. 50872148).

Contributing Institute(s):
  1. Streumethoden (IFF-4)
  2. Neutronenstreuung (IFF-5)
  3. Jülich-Aachen Research Alliance - Fundamentals of Future Information Technology (JARA-FIT)
  4. JCNS (Jülich Centre for Neutron Science JCNS (JCNS) ; JCNS)
Research Program(s):
  1. BioSoft: Makromolekulare Systeme und biologische Informationsverarbeitung (P45)
  2. Großgeräte für die Forschung mit Photonen, Neutronen und Ionen (PNI) (P55)

Appears in the scientific report 2010
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 Record created 2012-11-13, last modified 2024-06-19



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