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000009913 0247_ $$2DOI$$a10.1016/j.actamat.2010.03.007
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000009913 084__ $$2WoS$$aMaterials Science, Multidisciplinary
000009913 084__ $$2WoS$$aMetallurgy & Metallurgical Engineering
000009913 1001_ $$0P:(DE-HGF)0$$aLi, J.-B.$$b0
000009913 245__ $$aStructural evolution and physical properties of Bi1-xGdxFeO3 ceramics
000009913 260__ $$aAmsterdam [u.a.]$$bElsevier Science$$c2010
000009913 300__ $$a3701 - 3708
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000009913 440_0 $$067$$aActa Materialia$$v58$$x1359-6454$$y10
000009913 500__ $$aThis work is supported by National Basic Research Program of China (No. 2007CB925003) and National Natural Science Foundation of China (No. 50872148).
000009913 520__ $$aThe crystal structure and physical properties of Bi1-xGdxFeO3 ceramics with x <= 0.5 have been studied by X-ray diffraction, differential scanning calorimetry, dielectric and magnetic measurements. Bi1-xGdxFeO3 compounds crystallize at room temperature in R3c structure for x < 0.08 and in Pbnin structure for x >= 0.3. The R3c phase transforms to the Pbnm phase as temperature increases. Temperature-dependent dielectric response and low-temperature X-ray diffraction indicate a phase transition of the Pbnm phase at low-temperature. Detailed structural analysis indicates that the interaction between Bi and O plays an important role in the evolution of structure and physical properties. A phase diagram is constructed to illustrate the physical property composition temperature relations. (C) 2010 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.
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000009913 65320 $$2Author$$aBi-based magnetoelectric perovskites
000009913 65320 $$2Author$$aCrystal structure
000009913 65320 $$2Author$$aPhase transformation
000009913 65320 $$2Author$$aX-ray diffraction
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000009913 7001_ $$0P:(DE-HGF)0$$aRao, G.H.$$b1
000009913 7001_ $$0P:(DE-Juel1)131047$$aXiao, Y.$$b2$$uFZJ
000009913 7001_ $$0P:(DE-HGF)0$$aLiang, J. K.$$b3
000009913 7001_ $$0P:(DE-HGF)0$$aLuo, J.$$b4
000009913 7001_ $$0P:(DE-HGF)0$$aLiu, G. Y.$$b5
000009913 7001_ $$0P:(DE-HGF)0$$aChen, J. R.$$b6
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000009913 8567_ $$uhttp://dx.doi.org/10.1016/j.actamat.2010.03.007
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