| Home > Workflow collections > Publication Charges > Blended Salt Electrolyte Design for Enhanced NMC811||Graphite Cell Performance > print |
| 001 | 1020973 | ||
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| 100 | 1 | _ | |a Yan, Peng |0 P:(DE-Juel1)186842 |b 0 |u fzj |
| 245 | _ | _ | |a Blended Salt Electrolyte Design for Enhanced NMC811||Graphite Cell Performance |
| 260 | _ | _ | |a Weinheim |c 2024 |b Wiley-VCH |
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| 520 | _ | _ | |a The high energy density, nickel-rich layered cathode material LiNi0.8Mn0.1Co0.1O2(NMC811) is recognized as a promising candidate for next-generation batterychemistries. However, due to their structural and interfacial instability, nickel-richNMC cathodes still face a number of challenges in practical application. For thisreason, the design and development of novel electrolyte formulations, able tostabilize the nickel-rich cathode|electrolyte interface, are highly demanded. In thiswork, a novel electrolyte is developed using lithium (difluoromethanesulfonyl)(trifluoromethanesulfonyl)imide (LiDFTFSI) and lithium hexafluorophosphate(LiPF6) as salt blend in an organic carbonate-solvent based solvent mixture. Thepresence of LiDFTFSI notably enhances the electrochemical performance of theresulting NMC811||graphite cells. Further advancement of the considered cellchemistry is achieved by introducing the well-known functional electrolyteadditive vinylene carbonate (VC), which was found to feature a synergistic effectwith LiDFTFSI. The formation of a homogenous, effective, and robust solidelectrolyte interphase (SEI) as well as cathode electrolyte interphase (CEI) on thecorresponding electrodes resulted in superior electrochemical performance. |
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