Journal Article FZJ-2025-02809

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Performance improvements through gradient layers in transparent passivating contact solar cells

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2025
Cell Press Maryland Heights, MO

Cell reports / Physical science 6, 102658 () [10.1016/j.xcrp.2025.102658]

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Abstract: Transparent passivating contact solar cells using hydrogenated n-type nanocrystalline silicon carbide (nc-SiC:H(n)) utilize a double-layer stack consisting of one passivation-optimized and one conduction-optimized nc-SiC:H(n) layer. This double-layer configuration limits the fill factor (FF) due to the passivating layer’s low electrical conductivity. This study enhances this structure by introducing a gradient layer that transitions from passivating-like to conducting-like properties. While replacing the passivating layer alone does not improve performance, when combining it with an ultrathin passivating seed layer, the gradient layer effectively balances voltage and FF trade-offs. This results in higher device voltage and FF. Microstructural analysis shows hydrogen content near the crystalline Si interface similar to the double-layer approach but with increased electrical conductivity earlier in the layer stack. These improvements boost both FF and open-circuit voltage by 0.6% absolute and over 4 mV, respectively.

Classification:

Contributing Institute(s):
  1. Photovoltaik (IMD-3)
Research Program(s):
  1. 1212 - Materials and Interfaces (POF4-121) (POF4-121)

Appears in the scientific report 2025
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Medline ; Creative Commons Attribution CC BY 4.0 ; DOAJ ; OpenAccess ; Article Processing Charges ; Clarivate Analytics Master Journal List ; Current Contents - Engineering, Computing and Technology ; Current Contents - Physical, Chemical and Earth Sciences ; DOAJ Seal ; Essential Science Indicators ; Fees ; IF >= 5 ; JCR ; SCOPUS ; Science Citation Index Expanded ; Web of Science Core Collection
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 Datensatz erzeugt am 2025-06-17, letzte Änderung am 2025-09-17


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