| Hauptseite > Publikationsdatenbank > Impact of Ultrathin Electron-Selective Contacts on Perovskite–Silicon Tandem Solar Cells |
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| Journal Article | FZJ-2026-02313 |
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2026
American Chemical Society
Washington, DC
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Please use a persistent id in citations: doi:10.1021/acsenergylett.5c04082 doi:10.34734/FZJ-2026-02313
Abstract: During the development of perovskite–silicon tandem solar cells, the impact of transport layers of perovskite top cells on the short-circuit current density (JSC) has rarely been considered. Here, we report ultrathin electron-selective contacts as new architectures of electron transport layers (ETLs) by decreasing the C60 thickness to 1 nm, where the carrier collection efficiency is proven to be independent of C60 thickness with tin oxide as a buffer layer. Benefiting from the lowest C60 parasitic absorption, the JSC in the tandem device with ultrathin C60 is enhanced by 0.24 mA/cm2. Moreover, to recover the damage from atomic layer deposition on uncovered perovskite surface, we use poly(methyl methacrylate) (PMMA) as a protective layer. Combining ultrathin C60 and PMMA protective layer, an efficiency of 31.70% is finally achieved in tandem solar cells. These findings demonstrate the feasibility of ultrathin ETLs or ETL-free designs for perovskite–silicon tandem solar cells.
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