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Journal Article FZJ-2026-02313

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Impact of Ultrathin Electron-Selective Contacts on Perovskite–Silicon Tandem Solar Cells

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2026
American Chemical Society Washington, DC

ACS energy letters 11(4), 3250 - 3257 () [10.1021/acsenergylett.5c04082]

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Abstract: During the development of perovskite–silicon tandem solar cells, the impact of transport layers of perovskite top cells on the short-circuit current density (JSC) has rarely been considered. Here, we report ultrathin electron-selective contacts as new architectures of electron transport layers (ETLs) by decreasing the C60 thickness to 1 nm, where the carrier collection efficiency is proven to be independent of C60 thickness with tin oxide as a buffer layer. Benefiting from the lowest C60 parasitic absorption, the JSC in the tandem device with ultrathin C60 is enhanced by 0.24 mA/cm2. Moreover, to recover the damage from atomic layer deposition on uncovered perovskite surface, we use poly(methyl methacrylate) (PMMA) as a protective layer. Combining ultrathin C60 and PMMA protective layer, an efficiency of 31.70% is finally achieved in tandem solar cells. These findings demonstrate the feasibility of ultrathin ETLs or ETL-free designs for perovskite–silicon tandem solar cells.

Classification:

Contributing Institute(s):
  1. Photovoltaik (IMD-3)
Research Program(s):
  1. 1213 - Cell Design and Development (POF4-121) (POF4-121)

Appears in the scientific report 2026
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Medline ; Creative Commons Attribution CC BY 4.0 ; OpenAccess ; Clarivate Analytics Master Journal List ; Current Contents - Engineering, Computing and Technology ; Current Contents - Physical, Chemical and Earth Sciences ; Essential Science Indicators ; IF >= 20 ; JCR ; SCOPUS ; Science Citation Index Expanded ; Web of Science Core Collection
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Institutssammlungen > IMD > IMD-3
Workflowsammlungen > Öffentliche Einträge
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Open Access

 Datensatz erzeugt am 2026-04-24, letzte Änderung am 2026-06-01


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