Journal Article PreJuSER-13704

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Switching slow relaxation in a MnIII3MnIV cluster: an example of grafting single-molecule magnets onto polyoxometalates

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2010
Soc. Cambridge

Chemical communications 46, 2760 - 2762 () [10.1039/b925947c]

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Abstract: Binding an established single-molecule magnet cluster of distorted cubane type [Mn(III)(3)Mn(IV)O(4)] to the lacunary site of an {alpha-P(2)W(15)} polyoxotungstate scaffold results in a surprising zero-field splitting inversion and the subsequent loss of magnetization bistability.

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Note: Support for this work by the NSC, Taiwan, and ROC through the project NSC-98-2113-M-008-009 is greatly acknowledged.

Contributing Institute(s):
  1. Elektronische Eigenschaften (IFF-9)
Research Program(s):
  1. Grundlagen für zukünftige Informationstechnologien (P42)

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