Journal Article PreJuSER-13763

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Possible magnetic order and suppression of superconductivity by V doping in Sr2VO3FeAs

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2010
APS College Park, Md.

Physical review / B 82(14), 140507 () [10.1103/PhysRevB.82.140507]

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Abstract: Superconductivity at 33 K in Sr2VO3FeAs is completely suppressed by small amounts of V doping in Sr2VO3(Fe0.93(+/- 0.01)V0.07(+/- 0.01))As. The crystal structures and exact stoichiometries are determined by combined neutron powder diffraction and x-ray powder diffraction. Sr2VO3FeAs is shown to be very sensitive to Fe/V mixing, which interferes with or even suppresses superconductivity. This inhomogeneity may be intrinsic and explains scattered reports regarding T-c and reduced superconducting phase fractions in Sr2VO3FeAs. Neutron-diffraction data collected at 4 K indicate incommensurate magnetic ordering of the V sublattice with a propagation vector q approximate to(0,0,0.306). This suggests strongly correlated vanadium, which does not contribute significantly to the Fermi surface of Sr2VO3FeAs.

Keyword(s): J


Note: This work was financially supported by the German Research Foundation (DFG), under Project No. JO257/6-1.

Contributing Institute(s):
  1. Streumethoden (IFF-4)
  2. Neutronenstreuung (IFF-5)
  3. JCNS (Jülich Centre for Neutron Science JCNS (JCNS) ; JCNS)
Research Program(s):
  1. Großgeräte für die Forschung mit Photonen, Neutronen und Ionen (PNI) (P55)
  2. BioSoft: Makromolekulare Systeme und biologische Informationsverarbeitung (P45)
Experiment(s):
  1. DNS: Diffuse scattering neutron time of flight spectrometer (NL6S)
  2. SPODI: High resolution powder diffractometer (SR8a)

Appears in the scientific report 2010
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 Record created 2012-11-13, last modified 2025-01-29