An electric-field induced dynamical state in dispersions of charged colloidal rods

Dhont, Jan K.G.; Kang, Kyongok

doi:10.1039/c3sm52277f

Journal Article

FZJ-2014-01416

An electric-field induced dynamical state in dispersions of charged colloidal rods

Dhont, J. K. G. (Corresponding author)FZJ* ; Kang, K.FZJ*

2014
Royal Society of Chemistry (RSC) Cambridge

Soft matter 10(12), 1987-2007 (2014) [10.1039/c3sm52277f]

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Please use a persistent id in citations: http://hdl.handle.net/2128/5945 doi:10.1039/c3sm52277f

Abstract: The response of concentrated dispersions of charged colloids to low-frequency electric fields is governed by field-induced inter-colloidal interactions resulting from the polarization of electric double layers and the layer of condensed ions, association and dissociation of condensed ions, as well as hydrodynamic interactions through field-induced electro-osmotic flow. The phases and states that can be formed by such field-induced interactions are an essentially unexplored field of research. Experiments on concentrated suspensions of rod-like colloids (fd-virus particles), within the isotropic–nematic phase coexistence region, showed that a number of phases/states are induced, depending on the field amplitude and frequency [Soft Matter, 2010, 6, 273]. In particular, a dynamical state is found where nematic domains form and melt on a time scale of the order of seconds. We discuss the microscopic origin of this dynamical state, which is attributed to the cyclic, electric-field induced dissociation and association of condensed ions. A semi-quantitative theory is presented for the dynamics of melting and formation of nematic domains, including a model for the field-induced dissociation/association of condensed ions. The resulting equation of motion for the orientational order parameter is solved numerically for parameters complying with the fd-virus system. A limit-cycle is found, with a cycling-time that diverges at the transition line in the field-amplitude versus frequency plane where the dynamical state first appears, in accord with experimental findings.

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