Journal Article PreJuSER-16775

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Mesoscale hydrodynamic modeling of a colloid in shear-thinning viscoelastic fluids under shear flow

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2011
American Institute of Physics Melville, NY

The journal of chemical physics 135, 134116 () [10.1063/1.3646307]

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Abstract: In order to study the dynamics of colloidal suspensions with viscoelastic solvents, a simple mesoscopic model of the solvent is required. We propose to extend the multiparticle collision dynamics (MPC) technique--a particle-based simulation method, which has been successfully applied to study the hydrodynamic behavior of many complex fluids with Newtonian solvent--to shear-thinning viscoelastic solvents. Here, the normal MPC particles are replaced by dumbbells with finite-extensible nonlinear elastic (FENE) springs. We have studied the properties of FENE-dumbbell fluids under simple shear flow with shear rate ̇γ. The stress tensor is calculated, and the viscosity η and the first normal-stress coefficient Ψ(1) are obtained. Shear-thinning behavior is found for reduced shear rates Γ= ̇γτ>1, where τ is a characteristic dumbbell relaxation time. Here, both η and Ψ(1) display power-law behavior in the shear-thinning regime. Thus, the FENE-dumbbell fluid with MPC collisions provides a good description of viscoelastic fluids. As a first application, we study the flow behavior of a colloid in a shear-thinning viscoelastic fluid in two dimensions. A slowing down of the colloid rotation in a viscoelastic fluid compared to a Newtonian fluid is obtained, in agreement with recent numerical calculations and experimental results.

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Note: We thank Jan Vermant (Leuven), Ingo O. Gotze, and Chien-Cheng Huang (Julich) for stimulating discussions. Financial support by the EU FP7 Collaborative Research Project "Nanodirect" (NMP4-SL-2008-213948) is gratefully acknowledged.

Contributing Institute(s):
  1. Theorie der weichen Materie und Biophysik (ICS-2)
  2. Theorie der Weichen Materie und Biophysik (IAS-2)
Research Program(s):
  1. BioSoft: Makromolekulare Systeme und biologische Informationsverarbeitung (P45)

Appears in the scientific report 2011
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 Datensatz erzeugt am 2012-11-13, letzte Änderung am 2024-06-10


Published under German "Allianz" Licensing conditions on 2011-10-06. Available in OpenAccess from 2011-10-06:
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