Journal Article FZJ-2014-06419

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Al-Cr-Fe phase diagram. Isothermal sections in the region above 50 at% Al.

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2014
Elsevier Science Amsterdam [u.a.]

Calphad 45, 194 - 203 () [10.1016/j.calphad.2013.12.007]

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Abstract: The Al–Cr–Fe phase diagram was studied in the compositional range of 50–100 at% Al and partial isothermal sections were determined at 1160, 1100, 1075, 1042, 1000, 900, 800 and 700 °C. In the low-Al part of the studied compositional region the isostructural high-temperature Al–Cr and Al–Fe γ1-phases form a continuous region of solid solutions. Both binary Al13Fe4 and Al5Fe2 were found to dissolve up to 6.5 at% Cr while Al2Fe was found to extend up to 4.1 at% Cr. The solid solutions based on the Al–Cr γ2 and μ phases were determined to reach 35.2 and 1.3 at% Fe, respectively. The dissolution of Cr in the Al–Fe binaries only slightly influences their Al concentrations, while the Al–Cr binaries exhibit decreasing Al concentration with increasing Fe concentration. The Al–Cr η-phase dissolves up to 5 at% Fe, which results in a sharp decrease of its Al concentration and increase of melting temperatures. The earlier reported existence of a ternary decagonal D3-phase and three complex periodic phases O1, H and ε was confirmed and their compositions at different temperatures were specified.

Classification:

Contributing Institute(s):
  1. Mikrostrukturforschung (PGI-5)
Research Program(s):
  1. 424 - Exploratory materials and phenomena (POF2-424) (POF2-424)

Appears in the scientific report 2014
Database coverage:
Current Contents - Engineering, Computing and Technology ; Current Contents - Physical, Chemical and Earth Sciences ; IF < 5 ; JCR ; SCOPUS ; Science Citation Index ; Science Citation Index Expanded ; Thomson Reuters Master Journal List ; Web of Science Core Collection
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 Record created 2014-12-02, last modified 2024-06-10


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