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First-order virial expansion of short-time diffusion and sedimentation coefficients of permeable particles suspensions

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2011
American Institute of Physics [S.l.]

Physics of fluids 23, 083303 () [10.1063/1.3626196]

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Abstract: For suspensions of permeable particles, the short-time translational and rotational self-diffusion coefficients, and collective diffusion and sedimentation coefficients are evaluated theoretically. An individual particle is modeled as a uniformly permeable sphere of a given permeability, with the internal solvent flow described by the Debye-Bueche-Brinkman equation. The particles are assumed to interact non-hydrodynamically by their excluded volumes. The virial expansion of the transport properties in powers of the volume fraction is performed up to the two-particle level. The first-order virial coefficients corresponding to two-body hydrodynamic interactions are evaluated with very high accuracy by the series expansion in inverse powers of the inter-particle distance. Results are obtained and discussed for a wide range of the ratio, x, of the particle radius to the hydrodynamic screening length inside a permeable sphere. It is shown that for x greater than or similar to 10, the virial coefficients of the transport properties are well-approximated by the hydrodynamic radius (annulus) model developed by us earlier for the effective viscosity of porous-particle suspensions. (C) 2011 American Institute of Physics. [doi:10.1063/1.3626196]

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Note: M.L.E.J. and E.W. were supported in part by the Polish Ministry of Science and Higher Education Grant N N501 156538. G.N. thanks the Deutsche Forschungsgemeinschaft (SFB-TR6, project B2) for financial support.

Contributing Institute(s):
  1. Weiche Materie (ICS-3)
Research Program(s):
  1. BioSoft: Makromolekulare Systeme und biologische Informationsverarbeitung (P45)

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 Record created 2012-11-13, last modified 2024-06-19


Published under German "Allianz" Licensing conditions on 2011-08-31. Available in OpenAccess from 2011-08-31:
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