Journal Article FZJ-2015-01951

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A simple formulation of the CH2O photolysis quantum yields

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2015
EGU Katlenburg-Lindau

Atmospheric chemistry and physics / Discussions 15(5), 7239 - 7266 () [10.5194/acpd-15-7239-2015]

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Abstract: New expressions for the various wavelength – dependent photolysis quantum yields of CH2O, Φj, are presented. They are based on combinations of functions of the type Ai/(1 + exp[−(1/λ −1/λ 0i)/bi]). The parameters Ai, bi, and λ0i which have a physical meaning are obtained by fits to the measured data of the Φji available from the literature. The altitude dependence of the photolysis frequencies resulting from the new quantum yield expressions are compared to those derived from the Φj recommended by JPL and IUPAC.

Classification:

Contributing Institute(s):
  1. Troposphäre (IEK-8)
  2. Stratosphäre (IEK-7)
Research Program(s):
  1. 243 - Tropospheric trace substances and their transformation processes (POF3-243) (POF3-243)
  2. 244 - Composition and dynamics of the upper troposphere and middle atmosphere (POF3-244) (POF3-244)

Appears in the scientific report 2015
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Medline ; Creative Commons Attribution CC BY 3.0 ; DOAJ ; NCBI Molecular Biology Database
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