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Commensurate registry and chemisorptions at a hetero-organic interface

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2012
APS College Park, Md.

Physical review letters 108, 106103 () [10.1103/PhysRevLett.108.106103]

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Abstract: We present evidence for a partly chemisorptive bonding between single monolayers of copper-II-phthalocyanine (CuPc) and 3,4,9,10-perylene-tetracarboxylic-dianhydride (PTCDA) that are stacked on Ag(111). A commensurate registry between the two molecular layers and the substrate, i.e., a common crystallographic lattice for CuPc and PTCDA films as well as for the Ag(111) surface, indicates that the growth of the upper layer is dominated by the structure of the lower. Photoemission spectroscopy clearly reveals a gradual filling of the lowest unoccupied molecular orbital of PTCDA due to CuPc adsorption, which proves the chemisorptive character.

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Note: Record converted from VDB: 12.11.2012

Contributing Institute(s):
  1. Funktionale Nanostrukturen an Oberflächen (PGI-3)
  2. Jülich-Aachen Research Alliance - Fundamentals of Future Information Technology (JARA-FIT)
Research Program(s):
  1. Grundlagen für zukünftige Informationstechnologien (P42)

Appears in the scientific report 2012
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Medline ; American Physical Society Transfer of Copyright Agreement ; OpenAccess ; Current Contents - Social and Behavioral Sciences ; JCR ; NCBI Molecular Biology Database ; NationallizenzNationallizenz ; SCOPUS ; Science Citation Index ; Science Citation Index Expanded ; Thomson Reuters Master Journal List ; Web of Science Core Collection
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 Datensatz erzeugt am 2012-11-13, letzte Änderung am 2020-04-23


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