Journal Article

PreJuSER-22660

http://join2-wiki.gsi.de/foswiki/pub/Main/Artwork/join2_logo100x88.png Plutonium(VI) complexation by diglycolamide ligands coordination chemistry insight into TODGA-based actinide separations

Reilly, S. D. ; Gaunt, A. J. ; Scott, B. L. ; Modolo, G.FZJ* ; Iqbal, M. ; Verboom, W. ; Sarsfield, M. J.

2012
Soc. Cambridge

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Please use a persistent id in citations: http://hdl.handle.net/2128/7568  doi:10.1039/c2cc34967a

Abstract: Complexation of Pu(IV) with TMDGA, TEDGA, and TODGA diglycolamide ligands was followed by vis-NIR spectroscopy. A crystal structure determination reveals that TMDGA forms a 1 : 3 homoleptic Pu(IV) complex with the nitrate anions forced into the outer coordination sphere.

Keyword(s): J

Note: S.D.R. and A.J.G. thank the U.S. Department of Energy, Office of Science, Early Career Research Program (contract DE-AC52-06NA25396) for the Pu work which was conducted at LANL. M.I. thanks the Higher Education Commission of Pakistan for ligand syntheses work at the University of Twente. M.J.S. and G.M. thank the European Framework 'ACSEPT' project.

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Contributing Institute(s):

1. Sicherheitsforschung und Reaktortechnik (IEK-6)

Research Program(s):

1. Nukleare Sicherheitsforschung (P14)

Appears in the scientific report 2012

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Database coverage:
; ; Allianz-Lizenz / DFG ; Current Contents - Social and Behavioral Sciences ; JCR ; NCBI Molecular Biology Database ; Nationallizenz ; SCOPUS ; Science Citation Index ; Science Citation Index Expanded ; Thomson Reuters Master Journal List ; Web of Science Core Collection

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