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Coherent Dynamic Structure Factor of a Polymer Chain Confined Into a Harmonic Radial Potential

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2012
Wiley-VCH Weinheim

Macromolecular theory and simulations 21, 565 - 572 () [10.1002/mats.201200045]

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Abstract: The coherent dynamic structure factor of a single polymer chain is calculated based on the model of a Rouse polymer chain constrained (confined) by a harmonic radial potential and its behavior in different limiting cases is analyzed. The strength of confinement is characterized using an effective diameter of the harmonic radial potential as a model parameter. The method provides a reliable model to study the crossover between unconstrained (Rouse) and constrained dynamics.

Keyword(s): J ; linear (auto) ; nanoconfinement (auto) ; neutron scattering (auto) ; relaxation (auto) ; theory (auto)

Classification:

Note: The authors thank Dr. A. Wischnewski, Prof. N. F. Fatkullin, Prof. D. Richter, and Prof. A. Blumen for fruitful discussions. The support from the the DFG Priority Program SPP1369 "Polymer-Solid Contacts: Interfaces and Interphases" and the DFG funding grant Bl 142/11-1 are gratefully acknowledged.

Contributing Institute(s):
  1. Neutronenstreuung (ICS-1)
  2. Neutronenstreuung (JCNS-1)
Research Program(s):
  1. BioSoft: Makromolekulare Systeme und biologische Informationsverarbeitung (FUEK505) (FUEK505)
  2. 544 - In-house Research with PNI (POF2-544) (POF2-544)
Experiment(s):
  1. No specific instrument

Appears in the scientific report 2012
Database coverage:
JCR ; NationallizenzNationallizenz ; SCOPUS ; Science Citation Index ; Science Citation Index Expanded ; Thomson Reuters Master Journal List ; Web of Science Core Collection ; Zoological Record
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Dokumenttypen > Aufsätze > Zeitschriftenaufsätze
Institutssammlungen > JCNS > JCNS-1
Institutssammlungen > IBI > IBI-8
Workflowsammlungen > Öffentliche Einträge
ICS > ICS-1
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 Datensatz erzeugt am 2012-11-13, letzte Änderung am 2024-06-19



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