Journal Article PreJuSER-27263

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Rotational tracer diffusion in binary colloidal sphere mixtures

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2001
APS College Park, Md.

Physical review / E 64(2), 022401 () [10.1103/PhysRevE.64.022401]

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Abstract: We demonstrate that tracer/host size asymmetry and electrostatic interactions strongly affect rotational self-diffusion in binary mixtures of charged colloidal tracer and host spheres. Tracer diffusion coefficients, measured with time-resolved phosphorescence anisotropy, are compared with calculations of rotational diffusion including two- and three-particle hydrodynamic interactions. We also show that the inverse dependence of the rotational diffusion coefficient on the suspension viscosity is approached only at large size ratios.

Keyword(s): J


Note: Record converted from VDB: 12.11.2012

Contributing Institute(s):
  1. Weiche Materie (IFF-WM)
Research Program(s):
  1. Polymere, Membranen und komplexe Flüssigkeiten (23.30.0)

Appears in the scientific report 2001
Notes: This version is available at the following Publisher URL: http://pre.aps.org
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 Record created 2012-11-13, last modified 2024-06-19


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