| Home > Publications database > Fluorescence lifetimes and emission patterns probe the 3D orientation of the emitting chromophore in a multichromophoric system |
| Journal Article | PreJuSER-41754 |
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2004
American Chemical Society
Washington, DC
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Please use a persistent id in citations: http://hdl.handle.net/2128/678 doi:10.1021/ja0474603
Abstract: In this Communication, we report on the fluorescence behavior of an individual first generation multichromophoric dendrimer. The fact that each of the chromophores in time acts as a fluorescent trap is demonstrated by directly probing the dipole orientation of the emitting chromophore by means of defocused wide-field imaging and comparing experimental and calculated emission patterns. It is shown that in such cases the electromagnetic boundary condition effect results in discrete changes in the fluorescence lifetime as a function of time for individual dendrimers.
Keyword(s): J
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