| Home > Publications database > Sensitivity of biogenic silica oxygen isotopes to changes in surface water temperature and palaeoclimatology |
| Journal Article | PreJuSER-48547 |
; ;
2005
American Geophysical Union
Washington, DC
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Please use a persistent id in citations: http://hdl.handle.net/2128/20812 doi:10.1029/2004GL022167
Abstract: Oxygen isotope ratios of biogenic silica derived from planktonic diatoms living in the pelagial of a freshwater lake are used to determine the temperature effect on the isotope fractionation between water and biogenic silica under ecosystem conditions. Our data show a deterministic relation between seasonally changing water temperatures (4 degrees C-22 degrees C) and the oxygen isotope fractionation during valve formation. The temperature dependent fractionation appears to be independent of diatom cell sizes indicating a mere physical control of this process. The isotopic change induced per degree centigrade, the temperature coefficient, amounts to a value of -0.2 parts per thousand/degrees C. This implies that previous studies have overestimated the temperature relationship of this proxy by using coefficients of up to -0.5 parts per thousand/degrees C for climate reconstructions.
Keyword(s): J
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