Journal Article PreJuSER-55776

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Colloidal dynamics near a wall studied by evanescent wave light scattering: Experimental and theoretical improvements and methodological limitations

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2007
American Institute of Physics Melville, NY

The journal of chemical physics 126, 044707 () [10.1063/1.2431175]

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Abstract: The dynamics of colloidal spheres near to a wall is studied with an evanescent wave scattering setup that allows for an independent variation of the components of the scattering wave vector normal and parallel to the wall. The correlation functions obtained with this novel instrumentation are interpreted on the basis of an expression for their short time behavior that includes hydrodynamic interactions between the colloidal spheres and the wall. The combination of the evanescent wave scattering setup and the exact expression for the short time behavior of correlation functions allows for an unambiguous measurement of the particle mobility parallel and normal to the wall by means of light scattering. It is possible to measure the viscous wall drag effect on the dynamics of particles with radii as small as 27 nm, where, however, the method reaches its limits due to the low scattering intensities of such small particles.

Keyword(s): J


Note: Record converted from VDB: 12.11.2012

Contributing Institute(s):
  1. Weiche Materie (IFF-7)
Research Program(s):
  1. Kondensierte Materie (P54)

Appears in the scientific report 2007
Notes: This version is available at http://dx.doi.org/10.1063/1.2431175 Copyright © American Institute of Physics
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 Record created 2012-11-13, last modified 2024-06-19


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