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Polymer Chain Dynamics in a Random Environment: Heterogeneous Mobilities

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2007
APS College Park, Md.

Physical review letters 98, 168301 () [10.1103/PhysRevLett.98.168301]

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Abstract: We present a neutron scattering investigation on a miscible blend of two polymers with greatly different glass-transition temperatures T-g. Under such conditions, the nearly frozen high-T-g component imposes a random environment on the mobile chain. The results demand the consideration of a distribution of heterogeneous mobilities in the material and demonstrate that the larger scale dynamics of the fast component is not determined by the average local environment alone. This distribution of mobilities can be mapped quantitatively on the spectrum of local relaxation rates measured at high momentum transfers.

Keyword(s): J


Note: Record converted from VDB: 12.11.2012

Contributing Institute(s):
  1. Neutronenstreuung (IFF-5)
Research Program(s):
  1. Kondensierte Materie (P54)
  2. Großgeräte für die Forschung mit Photonen, Neutronen und Ionen (PNI) (P55)

Appears in the scientific report 2007
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American Physical Society Transfer of Copyright Agreement ; OpenAccess
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 Datensatz erzeugt am 2012-11-13, letzte Änderung am 2024-06-19


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