Journal Article

FZJ-2016-05003

http://join2-wiki.gsi.de/foswiki/pub/Main/Artwork/join2_logo100x88.png Singlet Oxygen Formation during the Charging Process of an Aprotic Lithium-Oxygen Battery

Wandt, J. (Corresponding author) ; Jakes, P. (Corresponding author)FZJ* ; Granwehr, J.FZJ* ; Gasteiger, H. A. ; Eichel, R.-A.FZJ*

2016
Wiley-VCH65543 Weinheim

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Please use a persistent id in citations: doi:10.1002/ange.201602142

Abstract: Aprotic lithium–oxygen (Li–O2) batteries have attracted considerable attention in recent years owing to their outstanding theoretical energy density. A major challenge is their poor reversibility caused by degradation reactions, which mainly occur during battery charge and are still poorly understood. Herein, we show that singlet oxygen (1Δg) is formed upon Li2O2 oxidation at potentials above 3.5 V. Singlet oxygen was detected through a reaction with a spin trap to form a stable radical that was observed by time- and voltage-resolved in operando EPR spectroscopy in a purpose-built spectroelectrochemical cell. According to our estimate, a lower limit of approximately 0.5 % of the evolved oxygen is singlet oxygen. The occurrence of highly reactive singlet oxygen might be the long-overlooked missing link in the understanding of the electrolyte degradation and carbon corrosion reactions that occur during the charging of Li–O2 cells.

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Contributing Institute(s):

1. Grundlagen der Elektrochemie (IEK-9)

Research Program(s):

1. 131 - Electrochemical Storage (POF3-131) (POF3-131)

Appears in the scientific report 2016

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Database coverage:
; NCBI Molecular Biology Database ; Nationallizenz ; No Authors Fulltext ; SCOPUS

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