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@ARTICLE{Mao:827783,
author = {Mao, Y. and Engels, J. and Houben, A. and Rasinski, M. and
Steffens, Jonathan and Terra, A. and Linsmeier, Ch. and
Coenen, J. W.},
title = {{T}he influence of annealing on yttrium oxide thin film
deposited by reactive magnetron sputtering: {P}rocess and
microstructure},
journal = {Nuclear materials and energy},
volume = {10},
issn = {2352-1791},
address = {Amsterdam [u.a.]},
publisher = {Elsevier},
reportid = {FZJ-2017-01887},
pages = {1 - 8},
year = {2017},
abstract = {Yttrium oxide thin films were prepared by reactive
magnetron sputtering in different deposition condition with
various oxygen flow rates. The annealing influence on the
yttrium oxide film microstructure is investigated. The
oxygen flow shows a hysteresis behavior on the deposition
rate. With a low oxygen flow rate, the so called metallic
mode process with a high deposition rate (up to 1.4 µm/h)
was achieved, while with a high oxygen flow rate, the
process was considered to be in the poisoned mode with an
extremely low deposition rate (around 20 nm/h). X-ray
diffraction (XRD) results show that the yttrium oxide films
that were produced in the metallic mode represent a mixture
of different crystal structures including the metastable
monoclinic phase and the stable cubic phase, while the
poisoned mode products show a dominating monoclinic phase.
The thin films prepared in metallic mode have relatively
dense structures with less porosity. Annealing at 600 °C
for 15 h, as a structure stabilizing process, caused a phase
transformation that changes the metastable monoclinic phase
to stable cubic phase for both poisoned mode and metallic
mode. The composition of yttrium oxide thin films changed
from nonstoichiometric to stoichiometric together with a
lattice parameter variation during annealing process. For
the metallic mode deposition however, cracks were formed due
to the thermal expansion coefficient difference between thin
film and the substrate material which was not seen in
poisoned mode deposition. The yttrium oxide thin films that
deposited in different modes give various application
options as a nuclear material.},
cin = {IEK-4},
ddc = {333.7},
cid = {I:(DE-Juel1)IEK-4-20101013},
pnm = {173 - Fusion Related Technology and Materials Research
(POF3-173) / HITEC - Helmholtz Interdisciplinary Doctoral
Training in Energy and Climate Research (HITEC)
(HITEC-20170406)},
pid = {G:(DE-HGF)POF3-173 / G:(DE-Juel1)HITEC-20170406},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000398974100001},
doi = {10.1016/j.nme.2016.12.031},
url = {https://juser.fz-juelich.de/record/827783},
}