| Home > Publications database > Capillary gas chromatography of polychlorinated benzonitriles (PCBN) |
| Journal Article | FZJ-2017-04660 |
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1997
Springer82386
Berlin
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Please use a persistent id in citations: doi:10.1007/s002160050632 doi:10.34734/FZJ-2017-04660
Abstract: Polychlorinated benzonitriles (PCBN) are products of combustion chemistry and can be emitted from municipal waste incinerators. Their possible relevance to environmental chemistry has not previously been described, with the exception of the herbicide 2,6-dichlorobenzonitrile. The isomer-specific separation and detection of the 19 PCBN congeners is performed by HRGC-ECD and HRGC-MSD. Commercially unavailable congeners were synthesized from chlorinated anilines and benzaldehydes. Retention data on three different stationary phases are given. Structure-retention relationships are discussed. A structure-specific systematic numbering of the 19 PCBN congeners is suggested.
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