Hauptseite > Publikationsdatenbank > Reactions of garnet-based solid-state lithium electrolytes with water — A depth-resolved study |
Journal Article | FZJ-2018-02666 |
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2018
Elsevier Science
Amsterdam [u.a.]
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Please use a persistent id in citations: http://hdl.handle.net/2128/18394 doi:10.1016/j.ssi.2018.03.004
Abstract: Garnet Li6.4La3Zr1.6Ta0.4O12 thin films prepared by magnetron sputtering were analysed by secondary ion mass spectrometry, nuclear reaction analysis and Rutherford backscattering to identify, localize and quantify the reactions associated with the presence of low amounts of water and carbon dioxide. Samples in a pristine state and after storage in an Argon-filled glove box for months were compared. Both, lithium hydroxide and lithium carbonate were detected, with carbon-containing species and hydrogen-containing having surprisingly different depth profiles.
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