Journal Article FZJ-2018-04632

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Coefficients of Thermal Expansion of Al- and Y-Substituted NaSICON Solid Solution Na3+2xAlxYxZr2−2xSi2PO12

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2018
MDPI Basel

Batteries 4(3), 33 () [10.3390/batteries4030033]

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Abstract: Because of an increasing interest in NaSICON materials as electrolyte materials in all-solid state sodium batteries, their thermal expansion was investigated in this study. The thermal expansion coefficient (CTE) of the Al and Y-substituted NaSICON compositions Na3+2xAlxYxZr2−2xSi2PO12 with 0 ≤ x ≤ 0.3 was obtained by dilatometry and compared to the CTE derived from the lattice parameters using high-temperature X-ray diffraction. The difference in CTE obtained from techniques, the influence of sodium content and central metal cation on CTE, as well as other observations such as phase changes are described and rationalized. View Full-Text

Classification:

Contributing Institute(s):
  1. Werkstoffsynthese und Herstellungsverfahren (IEK-1)
  2. Helmholtz-Institut Münster Ionenleiter für Energiespeicher (IEK-12)
Research Program(s):
  1. 131 - Electrochemical Storage (POF3-131) (POF3-131)
  2. SOFC - Solid Oxide Fuel Cell (SOFC-20140602) (SOFC-20140602)

Appears in the scientific report 2018
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Creative Commons Attribution CC BY 4.0 ; DOAJ ; OpenAccess ; Clarivate Analytics Master Journal List ; DOAJ Seal ; Emerging Sources Citation Index ; Web of Science Core Collection
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 Record created 2018-08-01, last modified 2024-07-12