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| 100 | 1 | _ | |a He, Xin |0 P:(DE-Juel1)169319 |b 0 |
| 245 | _ | _ | |a Fluorine-free water-in-ionomer electrolytes for sustainable lithium-ion batteries |
| 260 | _ | _ | |a [London] |c 2018 |b Nature Publishing Group UK |
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| 520 | _ | _ | |a The continuously increasing number and size of lithium-based batteries developed for large-scale applications raise serious environmental concerns. Herein, we address the issues related to electrolyte toxicity and safety by proposing a “water-in-ionomer” type of electrolyte which replaces organic solvents by water and expensive and toxic fluorinated lithium salts by a non-fluorinated, inexpensive and non-toxic superabsorbing ionomer, lithium polyacrylate. Interestingly, the electrochemical stability window of this electrolyte is extended greatly, even for high water contents. Particularly, the gel with 50 wt% ionomer exhibits an electrochemical stability window of 2.6 V vs. platinum and a conductivity of 6.5 mS cm−1 at 20 °C. Structural investigations suggest that the electrolytes locally self-organize and most likely switch local structures with the change of water content, leading to a 50% gel with good conductivity and elastic properties. A LiTi2(PO4)3/LiMn2O4 lithium-ion cell incorporating this electrolyte provided an average discharge voltage > 1.5 V and a specific energy of 77 Wh kg−1, while for an alternative cell chemistry, i.e., TiO2/LiMn2O4, a further enhanced average output voltage of 2.1 V and an initial specific energy of 124.2 Wh kg−1 are achieved. |
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| 700 | 1 | _ | |a Zhang, Xin |0 P:(DE-HGF)0 |b 2 |e Corresponding author |
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