Journal Article

FZJ-2019-02826

http://join2-wiki.gsi.de/foswiki/pub/Main/Artwork/join2_logo100x88.png Monitoring the morphological evolution in mixed-dimensional lead bromide perovskite film with lamellar-stacked perovskite nanoplatelets

Wang, R.FZJ* ; Tong, Y. ; Wang, K. ; Xia, S. ; Kentzinger, E.FZJ* ; Soltwedel, O. ; Müller-Buschbaum, P. (Corresponding author) ; Frielinghaus, H. (Corresponding author)FZJ*

2019
Royal Society of Chemistry Cambridge

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Please use a persistent id in citations: doi:10.1039/C9NH00156E

Abstract: Mixed-dimensional lead bromide perovskite films combine the properties of both three-dimensional (3D) and two-dimensional (2D) perovskite crystals, and due to their good humidity tolerance, they emerge as promising candidates for long-term stable optoelectronic applications. In order to further tailor the film morphology aiming for a better device performance, it is important to unravel the structural formation mechanism in these perovskite thin films. In the present study, the formation of 3D lead bromide perovskite crystals and the self-assembly of lamellar-stacked 2D perovskite nanoplatelets are comprehensively studied. Samples are prepared through a two-step vapor assisted route with different vapor exposure times in order to monitor the detailed morphology at the specific reaction stage. With grazing incidence X-ray scattering techniques, the preferential orientation of the 3D crystals is found to decrease upon increasing the reaction time. Also, it is evidenced that well-ordered in-plane lamellar-stacked 2D nanoplatelets form aggregates in the bulk structure only. The obtained hierarchical morphology shows excellent structural stability in a humid atmosphere even at a relative humidity level of 80%. Our findings statistically offer a morphological understanding, which is important for the optimization of the sample preparation route and thus the resulting performance of moisture-tolerant perovskite based optoelectronic devices.

Keyword(s): Chemical Reactions and Advanced Materials (1st) ; Materials Science (2nd)

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Contributing Institute(s):

1. JCNS-FRM-II (JCNS-FRM-II)
2. Heinz Maier-Leibnitz Zentrum (MLZ)
3. Neutronenstreuung (JCNS-1)
4. Streumethoden (JCNS-2)

Research Program(s):

1. 144 - Controlling Collective States (POF3-144) (POF3-144)
2. 6213 - Materials and Processes for Energy and Transport Technologies (POF3-621) (POF3-621)
3. 6G4 - Jülich Centre for Neutron Research (JCNS) (POF3-623) (POF3-623)
4. 6G15 - FRM II / MLZ (POF3-6G15) (POF3-6G15)

Experiment(s):

1. KWS-1: Small angle scattering diffractometer (NL3b)
2. NREX: Neutron reflectometer with X-ray option (NL1)

Appears in the scientific report 2019

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Database coverage:
Clarivate Analytics Master Journal List ; Current Contents - Engineering, Computing and Technology ; Current Contents - Physical, Chemical and Earth Sciences ; IF >= 5 ; JCR ; National-Konsortium ; SCOPUS ; Science Citation Index Expanded ; Web of Science Core Collection

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